42, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2017, 02, 18, 2017, 12, 07 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 23 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #9 -- TER - THU ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R1 R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 33921, 33940, 33930, -9999.000, 5.880, -9999.000 33941, 33960, 33950, 0.085, 6.046, 0.262 33961, 33980, 33970, 0.085, 6.212, 5.039 33981, 34000, 33990, 0.031, 5.520, 1.020 34001, 34020, 34010, 0.031, 5.156, 2.495 34021, 34040, 34030, 0.019, 4.148, 0.973 34041, 34060, 34050, 0.019, 3.140, -9999.000 34061, 34080, 34070, 0.006, 5.079, 1.902 34081, 34100, 34090, 0.006, 4.731, 2.276 34101, 34120, 34110, -0.019, 4.924, 0.944 34121, 34140, 34130, -0.019, 5.117, 1.394 34141, 34160, 34150, 0.022, 4.855, 0.493 34161, 34180, 34170, 0.022, 4.183, 0.001 34181, 34200, 34190, 0.013, 3.624, 1.160 34201, 34220, 34210, 0.013, 3.068, 0.990 34221, 34240, 34230, 0.011, 3.427, 0.011 34241, 34260, 34250, 0.011, 3.151, 0.133 34261, 34280, 34270, 0.033, 2.875, -0.336 34281, 34300, 34290, 0.033, 2.598, -0.055 34301, 34320, 34310, -0.008, 2.321, 0.461 34321, 34340, 34330, -0.008, 2.043, 0.482 34341, 34360, 34350, 0.018, 1.766, 0.359 34361, 34380, 34370, 0.018, 1.490, 0.663 34381, 34400, 34390, 0.045, 2.918, 1.935 34401, 34421, 34410, 0.045, 4.433, -0.484 34422, 34441, 34431, 0.008, 3.829, 0.316 34442, 34461, 34451, 0.008, 3.229, 0.883 34462, 34481, 34471, 0.041, 3.100, 0.453 34482, 34501, 34491, 0.041, 3.318, 0.531 34502, 34521, 34511, 0.000, 2.926, 0.679 34522, 34541, 34531, 0.000, 2.533, 0.964 34542, 34561, 34551, 0.079, 2.902, 0.516 34562, 34581, 34571, 0.079, 2.423, 1.627 34582, 34601, 34591, 0.007, 2.249, 0.646 34602, 34621, 34611, 0.007, 2.077, -0.732 34622, 34641, 34631, 0.049, 1.723, 1.006 34642, 34661, 34651, 0.049, 1.836, 0.968 34662, 34681, 34671, -0.022, 1.791, 0.515 34682, 34701, 34691, -0.022, 1.746, 0.491 34702, 34721, 34711, 0.081, 2.381, -0.233 34722, 34741, 34731, 0.081, 1.906, 0.171 34742, 34761, 34751, 0.062, 1.897, 0.324 34762, 34781, 34771, 0.062, 1.888, -0.121 34782, 34801, 34791, 0.029, 1.703, -0.192 34802, 34821, 34811, 0.029, 1.822, -0.191 34822, 34841, 34831, 0.040, 1.909, 0.604 34842, 34861, 34851, 0.040, 1.997, -0.078 34862, 34881, 34871, 0.091, 2.611, -0.563 34882, 34901, 34891, 0.091, 2.538, 0.268 34902, 34921, 34911, 0.095, 2.844, 0.689 34922, 34941, 34931, 0.095, 3.151, -0.496 34942, 34961, 34951, 0.073, 2.933, -0.364 34962, 34981, 34971, 0.073, 2.884, 0.587 34982, 35001, 34991, 0.052, 2.641, -0.309 35002, 35021, 35011, 0.052, 2.398, 0.272 35022, 35042, 35031, 0.056, 2.803, -0.635 35043, 35062, 35052, 0.056, 3.214, -0.621 35063, 35082, 35072, 0.091, 3.418, -0.541 35083, 35102, 35092, 0.091, 3.623, -0.229 35103, 35122, 35112, 0.056, 3.697, -0.250 35123, 35142, 35132, 0.056, 4.192, 0.647 35143, 35162, 35152, 0.064, 3.527, 0.411 35163, 35187, 35172, 0.064, 2.861, 0.686 35274, 35298, 35288, 0.037, 3.876, -9999.000 35299, 35319, 35309, 0.037, 3.287, 0.477 35320, 35339, 35329, 0.022, 3.259, -0.399 35340, 35359, 35349, 0.022, 3.231, -0.377 35360, 35379, 35369, 0.105, 3.680, -0.135 35380, 35399, 35389, 0.105, 3.501, 0.217 35400, 35419, 35409, 0.007, 3.256, -0.546 35420, 35439, 35429, 0.007, 3.012, -0.340 35440, 35459, 35449, 0.096, 3.282, -0.046 35460, 35479, 35469, 0.096, 3.322, -0.447 35480, 35499, 35489, 0.053, 3.343, 0.112 35500, 35519, 35509, 0.053, 3.364, 0.666 35520, 35539, 35529, 0.031, 2.834, -0.101 35540, 35559, 35549, 0.031, 2.921, -0.916 35560, 35579, 35569, 0.074, 2.726, -9999.000 35580, 35599, 35589, 0.074, 2.532, -0.043 35600, 35619, 35609, 0.041, 3.255, -9999.000 35620, 35639, 35629, 0.041, 3.833, -0.133 35640, 35659, 35649, 0.051, 3.360, -9999.000 35660, 35679, 35669, 0.051, 2.887, 0.893 35680, 35699, 35689, 0.033, -9999.000, 0.374 35700, 35719, 35709, 0.033, -9999.000, -0.026 35720, 35739, 35729, 0.039, -9999.000, 0.508 35740, 35759, 35749, 0.039, 2.787, 0.508 35760, 35779, 35769, 0.085, 2.713, -0.030 35780, 35799, 35789, 0.085, 3.244, -0.576 35800, 35820, 35809, 0.061, 3.024, -0.591 35821, 35840, 35830, 0.061, 2.803, -0.267 35841, 35860, 35850, 0.026, 3.291, 0.825 35861, 35880, 35870, 0.026, 3.186, 0.596 35881, 35900, 35890, 0.065, 2.802, -9999.000 35901, 35920, 35910, 0.065, 2.417, 0.287 35921, 35940, 35930, 0.094, 3.179, -0.426 35941, 35960, 35950, 0.094, 3.342, -0.285 35961, 35980, 35970, 0.073, 3.240, 0.316 35981, 36000, 35990, 0.073, 3.139, -9999.000 36001, 36020, 36010, 0.095, 3.520, -0.077 36021, 36040, 36030, 0.095, 3.796, 0.346 36041, 36060, 36050, 0.041, 3.380, -0.313 36061, 36080, 36070, 0.041, 2.965, -9999.000 36081, 36100, 36090, 0.046, 3.317, -0.428 36101, 36120, 36110, 0.046, 3.697, 0.104 36121, 36140, 36130, 0.065, 3.389, 0.283 36141, 36160, 36150, 0.065, 3.080, -0.097 36161, 36180, 36170, 0.083, 4.050, -0.268 36181, 36200, 36190, 0.083, 3.949, 0.201 36201, 36220, 36210, 0.049, 3.940, -9999.000 36221, 36240, 36230, 0.049, 3.931, -9999.000 36241, 36260, 36250, 0.071, 4.457, 0.019 36261, 36280, 36270, 0.071, 4.211, -0.046 36281, 36300, 36290, 0.081, 3.927, -0.091 36301, 36320, 36310, 0.081, 3.643, 0.107 36321, 36340, 36330, 0.065, 3.672, -0.173 36341, 36360, 36350, 0.065, 3.492, -0.434 36361, 36380, 36370, 0.080, 3.425, 0.633 36381, 36400, 36390, 0.080, 3.359, -9999.000 36401, 36420, 36410, 0.098, 3.788, -9999.000 36421, 36440, 36430, 0.098, 4.025, 0.398 36441, 36460, 36450, 0.078, 4.249, -0.483 36461, 36480, 36470, 0.078, 4.473, 1.414 36481, 36500, 36490, 0.086, 3.419, 0.714 36501, 36521, 36510, 0.086, 5.041, -9999.000 36522, 36541, 36531, 0.081, 4.516, 0.016 36542, 36561, 36551, 0.081, 3.993, 2.074 36562, 36581, 36571, 0.063, 5.043, -0.049 36582, 36601, 36591, 0.063, 4.912, -0.411 36602, 36621, 36611, 0.097, 4.638, -0.004 36622, 36641, 36631, 0.097, 4.364, -0.274 36642, 36661, 36651, 0.128, 4.838, -9999.000 36662, 36681, 36671, 0.128, 4.624, 0.024 36682, 36701, 36691, 0.089, 4.292, -9999.000 36702, 36721, 36711, 0.089, 3.961, -0.196 36722, 36741, 36731, 0.137, 4.882, 0.421 36742, 36761, 36751, 0.137, 4.526, 0.150 36762, 36781, 36771, 0.080, 4.776, -0.696 36782, 36801, 36791, 0.080, 5.026, 0.114 36802, 36821, 36811, 0.094, 4.507, 0.012 36822, 36841, 36831, 0.094, 4.062, -0.259 36842, 36861, 36851, 0.116, 3.952, 1.214 36862, 36881, 36871, 0.116, 3.843, -9999.000 36882, 36901, 36891, 0.085, 4.767, -0.711 36902, 36921, 36911, 0.085, 3.680, 1.253 36922, 36941, 36931, 0.080, 4.029, -0.413 36942, 36961, 36951, 0.080, 4.374, 0.462 36962, 36981, 36971, 0.128, 4.317, -9999.000 36982, 37001, 36991, 0.128, 4.110, -9999.000 37002, 37021, 37011, 0.099, 4.114, -0.266 37022, 37041, 37031, 0.099, 4.118, -9999.000 37042, 37061, 37051, 0.122, 4.557, -0.632 37062, 37081, 37071, 0.122, 4.565, -0.840 37082, 37101, 37091, 0.050, 4.655, 1.788 37102, 37121, 37111, 0.050, 4.745, 0.753 37122, 37141, 37131, 0.115, 4.680, -0.489 37142, 37161, 37151, 0.115, 4.953, -0.173 37162, 37181, 37171, 0.080, 4.429, -0.292 37182, 37201, 37191, 0.080, 3.905, -9999.000 37202, 37221, 37211, 0.069, 4.883, 0.160 37222, 37242, 37232, 0.069, 4.125, 0.434 37243, 37262, 37252, 0.115, 4.458, -0.448 37263, 37282, 37272, 0.115, 4.792, 0.593 37283, 37302, 37292, 0.085, 4.706, -9999.000 37303, 37322, 37312, 0.085, 4.612, 0.185 37323, 37342, 37332, 0.104, 4.282, -0.059 37343, 37362, 37352, 0.104, 3.951, -9999.000 37363, 37382, 37372, 0.053, 4.492, -9999.000 37383, 37402, 37392, 0.053, 4.302, 0.073 37403, 37422, 37412, 0.106, 4.486, 0.400 37423, 37442, 37432, 0.106, 4.670, -9999.000 37443, 37462, 37452, 0.092, 5.340, -0.160 37463, 37482, 37472, 0.092, 4.548, -9999.000 37483, 37502, 37492, 0.051, 4.451, -0.465 37503, 37522, 37512, 0.051, 4.354, -0.529 37523, 37542, 37532, 0.092, 4.804, 0.568 37543, 37562, 37552, 0.092, 4.965, -9999.000 37563, 37582, 37572, 0.068, 4.834, 0.344 37583, 37602, 37592, 0.068, 4.703, -9999.000 37603, 37622, 37612, 0.145, 4.935, 0.152 37623, 37642, 37632, 0.145, 4.628, 0.427 37643, 37662, 37652, 0.066, 4.107, -0.693 37663, 37682, 37672, 0.066, 3.586, 0.514 37683, 37702, 37692, 0.040, 4.755, -9999.000 37703, 37722, 37712, 0.040, 4.473, -9999.000 37723, 37742, 37732, 0.066, 3.958, -9999.000 37743, 37762, 37752, 0.066, 3.446, -9999.000 37763, 37782, 37772, 0.017, 3.179, -0.301 37783, 37802, 37792, 0.017, 3.365, 0.160 37803, 37822, 37812, 0.023, 3.054, 0.215 37823, 37842, 37832, 0.023, 2.743, 0.706 37843, 37863, 37853, 0.028, 3.469, -0.475 37864, 37883, 37873, 0.028, 4.238, 0.596 37884, 37903, 37893, 0.076, 3.614, -0.591 37904, 37923, 37913, 0.076, 2.990, 0.452 37924, 37943, 37933, 0.059, 3.136, -0.146 37944, 37963, 37953, 0.059, 3.808, 0.243 37964, 37983, 37973, 0.031, 3.809, -9999.000 37984, 38003, 37993, 0.031, 3.810, 0.196 38004, 38023, 38013, 0.036, 4.643, -0.021 38024, 38043, 38033, 0.036, 4.823, -9999.000 38044, 38063, 38053, 0.017, 4.359, 2.613 38064, 38083, 38073, 0.017, 3.893, 0.168 38084, 38103, 38093, 0.061, 5.845, -9999.000 38104, 38123, 38113, 0.061, 6.671, -0.216 38124, 38143, 38133, 0.058, 6.346, 1.450 38144, 38163, 38153, 0.058, 6.024, 0.504 38164, 38183, 38173, 0.076, 7.013, 0.085 38184, 38203, 38193, 0.076, 6.836, 1.057 38204, 38223, 38213, 0.050, 7.968, 1.665 38224, 38243, 38233, 0.050, 9.100, -0.054 38244, 38263, 38253, 0.030, 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