43, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2017, 02, 13, 2018, 02, 16 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 24 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #7 -- PUQ - ASI ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. ATHOS is calibrated with the new OH scavenging inlet. Differences with previous version due to improved calibration methods. OH & HO2 uncertainty ~1.32, 2 sigma confidence. Data in dense clouds is noisy, and is removed. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO works for conditions up to ambient NO ~20 ppbv; data are not recoverd for some low altitudes. REVISION: R2 R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 39664, 39683, 39678, -9999.000, 1.529, 1.217 39684, 39703, 39698, 0.024, 1.603, -9999.000 39704, 39723, 39718, 0.024, 1.545, 0.895 39724, 39743, 39738, -0.006, 1.487, -0.081 39744, 39763, 39758, -0.006, 1.588, 0.700 39764, 39783, 39778, 0.021, 1.670, 0.243 39784, 39803, 39798, 0.021, 1.780, 0.410 39804, 39823, 39818, -0.010, 1.891, 1.285 39824, 39843, 39838, -0.010, 1.351, -9999.000 39844, 39863, 39858, 0.006, 2.001, 0.170 39864, 39883, 39878, 0.006, 1.651, 0.363 39884, 39903, 39898, -0.012, 1.301, 0.250 39905, 39924, 39919, -0.012, 1.397, -0.237 39925, 39944, 39939, -0.009, 1.555, 0.357 39945, 39964, 39959, -0.009, 1.448, -0.479 39965, 39984, 39979, 0.020, 1.342, 0.175 39985, 40004, 39999, 0.020, 1.385, 0.467 40005, 40024, 40019, 0.011, 1.295, -0.396 40025, 40044, 40039, 0.011, 1.324, 0.213 40045, 40064, 40059, 0.008, 1.353, 0.365 40065, 40084, 40079, 0.008, 0.933, -0.506 40085, 40104, 40099, 0.018, 1.226, -0.304 40105, 40124, 40119, 0.018, 1.211, 0.235 40125, 40144, 40139, -0.010, 1.196, 0.244 40145, 40164, 40159, -0.010, 1.380, -0.555 40165, 40184, 40179, 0.002, 1.245, -0.116 40185, 40204, 40199, 0.002, 1.111, 1.161 40205, 40224, 40219, 0.055, 0.977, -0.473 40225, 40244, 40239, 0.055, 0.842, -0.232 40245, 40264, 40259, -0.028, 0.707, 0.681 40265, 40284, 40279, -0.028, 0.573, 0.518 40285, 40304, 40299, 0.014, 0.439, 0.268 40305, 40324, 40319, 0.014, 0.562, 0.034 40325, 40344, 40339, -9999.000, 0.111, 1.462 40345, 40364, 40359, -9999.000, -9999.000, -0.052 40365, 40384, 40379, 0.015, 1.461, -0.224 40385, 40404, 40399, 0.015, 2.019, -0.373 40405, 40424, 40419, 0.011, 2.061, 0.212 40425, 40444, 40439, 0.011, 2.127, -0.363 40445, 40464, 40459, 0.023, 2.193, 0.126 40465, 40484, 40479, 0.023, 2.029, 0.230 40486, 40505, 40500, 0.015, 2.528, 0.389 40506, 40525, 40520, 0.015, 2.714, -9999.000 40526, 40545, 40540, 0.038, 2.899, -0.498 40546, 40565, 40560, 0.038, 2.273, 0.260 40566, 40585, 40580, 0.051, 2.736, -0.051 40586, 40605, 40600, 0.051, 2.440, -9999.000 40606, 40625, 40620, 0.017, 2.143, -0.329 40626, 40645, 40640, 0.017, 2.295, 0.035 40646, 40665, 40660, 0.067, 2.511, -0.252 40666, 40685, 40680, 0.067, 2.704, -0.600 40686, 40705, 40700, 0.100, 2.897, 0.817 40706, 40725, 40720, 0.100, -9999.000, 0.954 40726, 40745, 40740, 0.078, -9999.000, 0.013 40746, 40765, 40760, 0.078, -9999.000, 0.459 40766, 40785, 40780, 0.050, 2.286, 0.410 40786, 40805, 40800, 0.050, 2.812, 0.302 40806, 40825, 40820, 0.072, 2.827, 1.072 40826, 40845, 40840, 0.072, 2.719, -9999.000 40846, 40865, 40860, 0.023, 2.612, 1.058 40866, 40885, 40880, 0.023, 2.311, -9999.000 40886, 40905, 40900, -0.016, 2.539, 0.103 40906, 40925, 40920, -0.016, 2.471, -9999.000 40926, 40945, 40940, 0.068, 2.403, -0.573 40946, 40965, 40960, 0.068, 2.338, 0.260 40966, 40985, 40980, 0.046, 2.527, -0.179 40986, 41005, 41000, 0.046, 2.777, -9999.000 41006, 41025, 41020, 0.026, 3.025, -0.026 41026, 41045, 41040, 0.026, 3.310, -9999.000 41046, 41065, 41060, 0.111, 2.938, -9999.000 41066, 41085, 41080, 0.111, 3.061, -9999.000 41086, 41105, 41100, 0.131, 3.184, 0.199 41106, 41125, 41120, 0.131, 2.629, -0.028 41126, 41145, 41140, 0.055, 3.071, -9999.000 41146, 41165, 41160, 0.055, 2.481, 1.986 41166, 41185, 41180, 0.044, 1.890, 1.077 41186, 41205, 41200, 0.044, 2.148, -0.075 41207, 41226, 41221, 0.035, -9999.000, -9999.000 41227, 41246, 41241, 0.035, -9999.000, -0.049 41307, 41326, 41321, -9999.000, -9999.000, -0.114 41327, 41346, 41341, -9999.000, -9999.000, 0.329 41347, 41366, 41361, -9999.000, -9999.000, -0.301 41367, 41386, 41381, -9999.000, -9999.000, 0.473 41387, 41406, 41401, -9999.000, -9999.000, 0.812 41407, 41426, 41421, -9999.000, -9999.000, 0.256 41427, 41446, 41441, -9999.000, -9999.000, -0.125 41467, 41486, 41481, -9999.000, -9999.000, 0.269 41507, 41526, 41521, -9999.000, -9999.000, 1.460 41527, 41546, 41541, -9999.000, -9999.000, -0.034 41547, 41566, 41561, -9999.000, -9999.000, 0.466 41567, 41586, 41581, -9999.000, 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4.429, 0.573 42200, 42219, 42214, 0.117, 5.085, 0.543 42220, 42239, 42234, 0.080, 4.655, -9999.000 42240, 42259, 42254, 0.080, 4.576, -9999.000 42260, 42279, 42274, 0.101, 4.498, -9999.000 42280, 42299, 42294, 0.101, 4.697, -9999.000 42301, 42320, 42315, 0.091, 5.474, -9999.000 42321, 42340, 42335, 0.091, 5.045, -9999.000 42341, 42360, 42355, 0.069, 4.615, -9999.000 42361, 42380, 42375, 0.069, 4.664, -9999.000 42381, 42400, 42395, 0.067, 4.834, -9999.000 42401, 42420, 42415, 0.067, 5.181, -9999.000 42421, 42440, 42435, 0.096, 5.528, -0.110 42441, 42460, 42455, 0.096, 4.607, -0.072 42461, 42480, 42475, 0.052, 4.507, -9999.000 42481, 42500, 42495, 0.052, 4.353, 0.429 42501, 42520, 42515, 0.099, 4.199, -9999.000 42521, 42540, 42535, 0.099, 4.975, -9999.000 42541, 42560, 42555, 0.119, 4.575, 0.907 42561, 42580, 42575, 0.119, 4.775, -9999.000 42581, 42600, 42595, 0.077, 4.978, -0.158 42601, 42620, 42615, 0.077, 5.038, 0.119 42621, 42640, 42635, 0.079, 4.934, -0.216 42641, 42660, 42655, 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