42, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2017, 02, 05, 2017, 12, 07 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 23 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #5 -- NAN - CHC ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R1 R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 76988, 77012, 76997, 0.295, 6.863, -9999.000 77101, 77125, 77115, 0.862, 14.494, -9999.000 77126, 77145, 77135, 0.862, 14.031, 0.272 77146, 77165, 77155, 0.549, 12.046, 0.012 77166, 77185, 77175, 0.549, 10.407, 0.530 77186, 77205, 77195, 0.292, 8.760, -0.004 77206, 77225, 77215, 0.292, 9.979, -0.466 77226, 77245, 77235, 0.329, 10.064, 0.143 77246, 77265, 77255, 0.329, 9.135, 0.115 77266, 77285, 77275, 0.440, 8.206, 0.791 77286, 77305, 77295, 0.440, 8.224, -0.333 77306, 77325, 77315, 0.281, 8.946, -9999.000 77326, 77345, 77335, 0.281, 9.087, 0.122 77346, 77365, 77355, 0.217, 9.227, -0.286 77366, 77385, 77375, 0.217, 8.898, -0.365 77386, 77405, 77395, 0.233, 9.158, -0.103 77406, 77425, 77415, 0.233, 9.137, 0.269 77426, 77446, 77435, 0.271, 9.115, -0.554 77447, 77466, 77456, 0.271, 8.143, -0.650 77467, 77486, 77476, 0.299, 10.752, -0.164 77487, 77506, 77496, 0.299, 10.107, 0.785 77507, 77526, 77516, 0.287, 9.462, 0.916 77527, 77546, 77536, 0.287, 6.651, 0.392 77547, 77566, 77556, 0.210, 5.822, 0.771 77567, 77586, 77576, 0.210, 7.856, 0.308 77587, 77606, 77596, 0.325, 9.911, 1.743 77607, 77626, 77616, 0.325, 9.619, 1.293 77627, 77646, 77636, 0.289, 10.586, 2.183 77647, 77666, 77656, 0.289, 9.959, 2.048 77667, 77686, 77676, 0.145, 9.329, 1.943 77687, 77706, 77696, 0.145, 10.386, 1.634 77707, 77726, 77716, 0.205, 9.344, 1.157 77727, 77746, 77736, 0.205, 9.224, 0.875 77747, 77766, 77756, 0.167, 9.104, 2.260 77767, 77786, 77776, 0.167, 9.816, 2.493 77787, 77806, 77796, 0.183, 8.880, 1.658 77807, 77826, 77816, 0.183, 9.338, 2.655 77827, 77846, 77836, 0.210, 9.797, 4.268 77847, 77866, 77856, 0.210, 9.344, -9999.000 77867, 77886, 77876, -9999.000, -9999.000, 1.996 77887, 77906, 77896, -9999.000, -9999.000, 0.306 77907, 77926, 77916, -9999.000, -9999.000, 3.097 77927, 77946, 77936, -9999.000, -9999.000, 3.844 77947, 77966, 77956, -9999.000, -9999.000, 2.655 77967, 77986, 77976, 0.085, 5.486, 1.062 77987, 78006, 77996, 0.063, 4.121, -9999.000 78007, 78026, 78016, 0.063, 9.838, -9999.000 78027, 78046, 78036, 0.107, 10.270, -9999.000 78047, 78066, 78056, 0.107, 8.581, -9999.000 78067, 78087, 78076, 0.049, 6.892, -9999.000 78088, 78112, 78097, 0.049, 6.757, -9999.000 78198, 78222, 78212, 0.103, 16.225, -9999.000 78223, 78242, 78232, 0.103, 14.600, 1.187 78243, 78262, 78252, 0.081, 12.990, -0.539 78263, 78282, 78272, 0.081, 17.085, 4.797 78283, 78302, 78292, 0.153, 16.246, 1.665 78303, 78322, 78312, 0.153, 19.337, -9999.000 78323, 78342, 78332, 0.233, 22.398, 0.869 78343, 78362, 78352, 0.233, 23.563, -9999.000 78363, 78382, 78372, 0.216, 17.433, -9999.000 78383, 78402, 78392, 0.216, 16.714, 1.889 78403, 78422, 78412, 0.101, 15.995, -9999.000 78423, 78442, 78432, 0.101, 16.253, 1.563 78443, 78462, 78452, 0.252, 15.208, 3.319 78463, 78482, 78472, 0.252, 15.101, 3.761 78483, 78502, 78492, 0.162, 14.994, 1.341 78503, 78522, 78512, 0.162, 16.819, 1.757 78523, 78542, 78532, 0.244, 18.084, 1.643 78543, 78562, 78552, 0.244, 16.006, 3.614 78563, 78583, 78572, 0.246, 13.919, 0.471 78584, 78603, 78593, 0.246, 14.470, 1.037 78604, 78623, 78613, 0.262, 12.659, 1.587 78624, 78643, 78633, 0.262, 12.641, 3.087 78644, 78663, 78653, 0.219, 12.623, 1.703 78664, 78683, 78673, 0.219, 13.852, 0.691 78684, 78703, 78693, 0.318, 11.978, 0.683 78704, 78723, 78713, 0.318, 11.278, 0.440 78724, 78743, 78733, 0.310, 10.577, 1.682 78744, 78763, 78753, 0.310, 13.486, 0.214 78764, 78783, 78773, 0.270, 7.138, -0.001 78784, 78803, 78793, 0.270, 9.168, 0.469 78804, 78823, 78813, 0.339, 11.198, 0.411 78824, 78843, 78833, 0.339, 11.722, 0.241 78844, 78863, 78853, 0.417, 11.637, 0.875 78864, 78883, 78873, 0.417, 12.262, 0.533 78884, 78903, 78893, 0.466, 12.887, -0.045 78904, 78923, 78913, 0.466, 13.538, -0.369 78924, 78943, 78933, 0.461, 12.954, -0.088 78944, 78963, 78953, 0.461, 13.513, 1.088 78964, 78983, 78973, 0.589, 14.073, 0.218 78984, 79003, 78993, 0.589, 12.930, 0.002 79004, 79023, 79013, 0.450, 13.919, 0.619 79024, 79043, 79033, 0.450, 11.953, 0.569 79044, 79063, 79053, 0.457, 9.997, 0.375 79064, 79083, 79073, 0.457, 10.966, 0.378 79084, 79103, 79093, 0.327, 13.141, 0.483 79104, 79124, 79113, 0.327, 12.331, -0.171 79125, 79144, 79134, 0.381, 11.522, -0.157 79145, 79164, 79154, 0.381, 11.703, 0.083 79165, 79184, 79174, 0.333, 11.126, 0.291 79185, 79204, 79194, 0.333, 11.503, 0.272 79205, 79224, 79214, 0.379, 11.880, -0.006 79225, 79244, 79234, 0.379, 10.674, 0.331 79245, 79264, 79254, 0.282, 9.729, 0.095 79265, 79284, 79274, 0.282, 10.482, 0.120 79285, 79304, 79294, 0.376, 11.235, 0.276 79305, 79324, 79314, 0.376, 10.452, -0.458 79325, 79344, 79334, 0.387, 10.307, 0.202 79345, 79364, 79354, 0.387, 8.985, -0.370 79365, 79384, 79374, 0.336, 7.675, 0.318 79385, 79404, 79394, 0.336, 9.374, -0.006 79405, 79424, 79414, 0.371, 10.180, -9999.000 79425, 79444, 79434, 0.371, 10.270, 0.333 79445, 79464, 79454, 0.488, 10.361, -0.024 79465, 79484, 79474, 0.488, 10.152, 0.129 79485, 79504, 79494, 0.553, 9.877, 0.143 79505, 79524, 79514, 0.553, 9.295, 0.051 79525, 79544, 79534, 0.412, 8.714, 0.138 79545, 79564, 79554, 0.412, 9.263, 0.604 79565, 79584, 79574, 0.551, 10.519, 0.253 79585, 79604, 79594, 0.551, 10.510, 0.775 79605, 79624, 79614, 0.565, 10.502, -0.019 79625, 79644, 79634, 0.565, 8.395, 0.240 79645, 79664, 79654, 0.631, 7.633, -0.346 79665, 79684, 79674, 0.631, 7.699, 0.497 79685, 79704, 79694, 0.535, 7.766, 0.077 79705, 79724, 79714, 0.535, 8.483, 0.249 79725, 79744, 79734, 0.334, 8.954, 0.412 79745, 79765, 79755, 0.334, 8.138, 0.101 79766, 79785, 79775, 0.334, 7.329, 0.241 79786, 79805, 79795, 0.334, 6.912, 0.390 79806, 79825, 79815, 0.394, 8.245, 0.267 79826, 79845, 79835, 0.394, 8.192, 0.437 79846, 79865, 79855, 0.458, 8.138, 0.505 79866, 79885, 79875, 0.458, 7.842, 0.456 79886, 79905, 79895, 0.384, 6.917, 0.416 79906, 79925, 79915, 0.384, 6.856, 0.296 79926, 79945, 79935, 0.308, 6.795, 0.244 79946, 79965, 79955, 0.308, -9999.000, 0.514 79966, 79985, 79975, 0.355, 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0.368, -9999.000, -0.163 80600, 80619, 80609, 0.368, -9999.000, -0.009 80620, 80639, 80629, 0.502, 7.675, 0.368 80640, 80659, 80649, 0.502, 9.011, -9999.000 80660, 80679, 80669, 0.426, 9.300, -0.023 80680, 80699, 80689, 0.426, 9.583, -9999.000 80700, 80719, 80709, 0.380, 9.867, 0.195 80720, 80739, 80729, 0.380, 8.305, -9999.000 80740, 80759, 80749, 0.276, 9.831, -9999.000 80760, 80779, 80769, 0.276, 9.779, -0.736 80780, 80799, 80789, 0.380, 9.727, -9999.000 80800, 80819, 80809, 0.380, 10.477, -0.440 80820, 80839, 80829, 0.294, 10.237, -0.177 80840, 80859, 80849, 0.294, 10.735, -0.625 80860, 80879, 80869, 0.233, 11.235, -0.610 80880, 80899, 80889, 0.233, 10.292, -0.701 80900, 80919, 80909, 0.415, 12.624, 0.323 80920, 80939, 80929, 0.415, 11.736, -0.395 80940, 80959, 80949, 0.381, 10.848, -0.812 80960, 80979, 80969, 0.381, 13.332, -1.257 80980, 80999, 80989, 0.504, 13.157, -0.017 81000, 81019, 81009, 0.504, 12.107, 0.212 81020, 81039, 81029, 0.288, 11.062, 0.486 81040, 81059, 81049, 0.288, 9.738, -0.141 81060, 81079, 81069, 0.173, 10.113, 1.041 81080, 81099, 81089, 0.173, 9.430, 0.618 81100, 81119, 81109, 0.136, 8.748, 0.567 81120, 81139, 81129, 0.136, 10.255, -0.158 81140, 81159, 81149, 0.246, 10.574, -0.731 81160, 81179, 81169, 0.246, 11.988, 3.282 81180, 81199, 81189, 0.153, 13.402, 1.553 81200, 81219, 81209, 0.153, 16.672, 0.874 81220, 81240, 81229, 0.330, 18.719, 0.667 81241, 81260, 81250, 0.330, 17.418, 0.877 81261, 81280, 81270, 0.221, 16.123, 4.364 81281, 81300, 81290, 0.221, 19.249, 0.900 81301, 81320, 81310, 0.162, 18.627, 0.392 81321, 81340, 81330, 0.162, 20.396, 0.980 81341, 81360, 81350, 0.275, 22.175, 3.672 81361, 81380, 81370, 0.275, 20.171, 1.857 81381, 81400, 81390, -9999.000, 18.489, 6.012 81421, 81440, 81430, 0.046, 14.778, -9999.000 81441, 81460, 81450, 0.046, 23.295, 2.278 81461, 81480, 81470, 0.100, -9999.000, -9999.000 81481, 81500, 81490, 0.100, 24.237, -9999.000 81501, 81520, 81510, 0.104, 23.119, -0.590 81521, 81540, 81530, 0.104, 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