48, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2017, 02, 03, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 30 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #4 -- KOA - NAN ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R4 R4: Final Data (see OTHER_COMMENTS) R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 68334, 68353, 68344, -9999.000, -9999.000 68354, 68373, 68364, -9999.000, -9999.000 68374, 68393, 68384, -9999.000, -9999.000 68394, 68413, 68404, -9999.000, -9999.000 68414, 68433, 68424, -9999.000, -9999.000 68434, 68453, 68444, -9999.000, -9999.000 68454, 68473, 68464, 0.081, 22.571 68474, 68493, 68484, 0.081, 20.358 68494, 68513, 68504, 0.027, 19.202 68514, 68533, 68524, 0.027, 18.243 68534, 68553, 68544, 0.083, 17.283 68554, 68573, 68564, 0.079, 17.842 68575, 68594, 68585, 0.079, 20.883 68595, 68614, 68605, 0.084, 22.442 68615, 68634, 68625, 0.084, 24.000 68635, 68654, 68645, 0.050, 21.134 68655, 68674, 68665, 0.050, 22.506 68675, 68694, 68685, 0.050, -9999.000 68695, 68714, 68705, -9999.000, -9999.000 68715, 68734, 68725, 0.096, 20.068 68735, 68754, 68745, 0.096, 12.447 68755, 68774, 68765, 0.096, 4.825 68775, 68794, 68785, 0.123, 5.798 68795, 68814, 68805, 0.123, 6.771 68815, 68834, 68825, 0.114, 7.743 68835, 68854, 68845, 0.114, 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