48, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2017, 02, 01, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 30 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #3 -- ANC - KOA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R4 R4: Final Data (see OTHER_COMMENTS) R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 72540, 72559, 72550, -9999.000, -9999.000 72560, 72579, 72570, -9999.000, -9999.000 72580, 72599, 72590, -9999.000, -9999.000 72600, 72619, 72610, -9999.000, -9999.000 72620, 72639, 72630, -9999.000, -9999.000 72640, 72659, 72650, -9999.000, -9999.000 72660, 72679, 72670, -0.006, 2.699 72680, 72699, 72690, 0.020, 2.351 72700, 72719, 72710, 0.013, 2.004 72720, 72739, 72730, 0.013, 1.685 72740, 72759, 72750, 0.013, 1.351 72760, 72779, 72770, 0.023, 1.435 72780, 72799, 72790, 0.023, 1.518 72931, 72950, 72941, -9999.000, -9999.000 72951, 72970, 72961, 0.036, 1.876 72971, 72990, 72981, 0.036, 1.758 72991, 73010, 73001, 0.036, 1.640 73011, 73030, 73021, 0.012, 1.818 73031, 73050, 73041, 0.012, 1.894 73051, 73070, 73061, -0.007, 2.058 73071, 73090, 73081, -0.009, 2.222 73091, 73110, 73101, -0.009, 2.034 73111, 73130, 73121, -0.009, 1.946 73131, 73150, 73141, -0.009, 1.538 73151, 73170, 73161, 0.004, 1.131 73171, 73190, 73181, 0.004, 1.467 73191, 73210, 73201, 0.004, 2.382 73212, 73231, 73222, 0.007, 2.145 73232, 73251, 73242, 0.007, 1.908 73252, 73271, 73262, 0.026, 1.672 73272, 73291, 73282, 0.002, 1.436 73292, 73311, 73302, 0.002, 1.200 73312, 73331, 73322, 0.002, 0.963 73332, 73351, 73342, 0.016, 1.851 73352, 73371, 73362, 0.004, 2.053 73372, 73391, 73382, 0.004, 2.017 73392, 73411, 73402, 0.017, 1.980 73412, 73431, 73422, 0.017, 1.534 73432, 73451, 73442, 0.017, 2.180 73452, 73471, 73462, 0.013, 2.034 73472, 73491, 73482, 0.026, 1.887 73492, 73511, 73502, 0.026, 2.064 73512, 73531, 73522, 0.026, 2.502 73532, 73551, 73542, 0.016, 2.513 73552, 73571, 73562, 0.016, 2.523 73572, 73591, 73582, 0.016, 2.295 73592, 73611, 73602, 0.042, 2.812 73612, 73631, 73622, 0.042, 2.637 73632, 73651, 73642, 0.015, 2.462 73652, 73671, 73662, 0.015, 2.303 73672, 73691, 73682, 0.015, 3.044 73692, 73711, 73702, 0.020, 2.936 73712, 73731, 73722, 0.034, 2.828 73732, 73751, 73742, 0.034, 2.947 73752, 73771, 73762, 0.021, 3.287 73772, 73791, 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