43, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2017, 02, 01, 2018, 02, 16 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 24 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #3 -- ANC - KOA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. ATHOS is calibrated with the new OH scavenging inlet. Differences with previous version due to improved calibration methods. OH & HO2 uncertainty ~1.32, 2 sigma confidence. Data in dense clouds is noisy, and is removed. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO works for conditions up to ambient NO ~20 ppbv; data are not recoverd for some low altitudes. REVISION: R2 R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 72556, 72575, 72570, -9999.000, 2.063, -9999.000 72576, 72595, 72590, 0.014, 1.663, -9999.000 72596, 72615, 72610, 0.014, 2.066, -9999.000 72616, 72635, 72630, -0.012, 2.471, -9999.000 72636, 72655, 72650, -0.012, 1.718, -9999.000 72656, 72675, 72670, 0.017, 1.642, -9999.000 72676, 72695, 72690, 0.017, 1.442, -9999.000 72696, 72715, 72710, 0.018, 1.243, -9999.000 72716, 72735, 72730, 0.018, 1.056, -9999.000 72736, 72755, 72750, -0.015, 0.861, -9999.000 72756, 72775, 72770, -0.015, 0.962, -9999.000 72776, 72795, 72790, -0.015, -9999.000, 6.834 72927, 72946, 72941, 0.029, -9999.000, -9999.000 72947, 72966, 72961, 0.029, 1.285, 8.009 72967, 72986, 72981, 0.029, 1.206, 7.023 72987, 73006, 73001, 0.031, 1.128, 7.144 73007, 73026, 73021, 0.031, 1.250, 8.048 73027, 73046, 73041, 0.007, 1.303, 5.140 73047, 73066, 73061, 0.007, 1.403, 4.693 73067, 73086, 73081, -0.024, 1.503, 4.672 73087, 73106, 73101, -0.024, 1.362, 2.893 73107, 73126, 73121, -0.023, 1.307, 3.915 73127, 73146, 73141, -0.023, 1.054, 1.813 73147, 73166, 73161, 0.011, 0.802, 2.385 73167, 73186, 73181, 0.011, 1.008, 1.998 73187, 73206, 73201, 0.017, 1.579, 2.525 73208, 73227, 73222, 0.017, 1.429, 1.116 73228, 73247, 73242, 0.034, 1.281, 2.614 73248, 73267, 73262, 0.034, 1.132, 1.937 73268, 73287, 73282, -0.004, 0.984, 1.932 73288, 73307, 73302, -0.004, 0.835, 1.314 73308, 73327, 73322, 0.019, 0.686, 0.980 73328, 73347, 73342, 0.019, 1.226, 1.145 73348, 73367, 73362, -0.013, 1.360, 1.321 73368, 73387, 73382, -0.013, 1.336, 1.124 73388, 73407, 73402, 0.032, 1.312, 1.103 73408, 73427, 73422, 0.032, 1.038, 1.326 73428, 73447, 73442, 0.013, 1.430, 0.891 73448, 73467, 73462, 0.013, 1.341, 1.364 73468, 73487, 73482, 0.037, 1.251, 1.742 73488, 73507, 73502, 0.037, 1.374, 1.127 73508, 73527, 73522, 0.020, 1.630, 0.998 73528, 73547, 73542, 0.020, 1.630, 0.801 73548, 73567, 73562, 0.010, 1.631, 0.411 73568, 73587, 73582, 0.010, 1.516, 0.417 73588, 73607, 73602, 0.057, 1.811, 1.140 73608, 73627, 73622, 0.057, 1.699, 0.802 73628, 73647, 73642, 0.035, 1.588, 0.821 73648, 73667, 73662, 0.035, 1.484, 0.753 73668, 73687, 73682, 0.011, 1.932, 0.936 73688, 73707, 73702, 0.011, 1.867, 0.756 73708, 73727, 73722, 0.033, 1.803, 0.580 73728, 73747, 73742, 0.033, 1.871, 0.476 73748, 73767, 73762, 0.049, 2.085, 0.550 73768, 73787, 73782, 0.049, 1.997, 0.385 73788, 73807, 73802, 0.035, 1.909, 1.202 73808, 73827, 73822, 0.035, 1.636, 1.219 73828, 73847, 73842, 0.061, 1.920, 0.364 73849, 73868, 73863, 0.061, 1.808, 1.383 73869, 73888, 73883, -0.026, 1.697, 0.870 73889, 73908, 73903, -0.026, 2.255, 0.963 73908, 73927, 73922, 0.033, 2.441, 0.709 73928, 73947, 73942, 0.033, 2.194, 1.450 73948, 73967, 73962, -0.004, 1.947, 1.139 73968, 73987, 73982, -0.004, -9999.000, 1.301 74271, 74290, 74285, -9999.000, -9999.000, 0.569 74291, 74310, 74305, 0.020, 1.827, 0.167 74311, 74330, 74325, 0.020, 1.898, 0.658 74331, 74350, 74345, 0.090, 1.051, 0.099 74351, 74370, 74365, 0.090, 1.193, 0.371 74371, 74390, 74385, 0.063, 1.334, 0.369 74391, 74410, 74405, 0.063, 1.543, 0.476 74411, 74430, 74425, 0.110, 1.518, 0.432 74431, 74450, 74445, 0.110, 1.627, 0.318 74556, 74575, 74570, -9999.000, 2.310, -9999.000 74577, 74596, 74591, 0.028, 1.868, -0.257 74597, 74616, 74611, 0.042, 2.422, -9999.000 74617, 74636, 74631, 0.042, 2.743, -9999.000 74637, 74656, 74651, 0.025, 3.066, 0.124 74657, 74676, 74671, 0.025, 2.625, 0.503 74677, 74696, 74691, 0.028, 2.746, 0.410 74697, 74716, 74711, 0.028, 2.585, 0.152 74717, 74736, 74731, 0.028, 2.425, 0.332 74737, 74756, 74751, 0.028, 2.753, -0.272 74757, 74776, 74771, -9999.000, -9999.000, 0.292 74777, 74796, 74791, -9999.000, -9999.000, 0.079 74797, 74816, 74811, -9999.000, -9999.000, 0.123 74817, 74836, 74831, -9999.000, -9999.000, 0.271 74837, 74856, 74851, -9999.000, -9999.000, 0.170 74877, 74896, 74891, -9999.000, -9999.000, -0.154 74897, 74916, 74911, -9999.000, -9999.000, 0.306 74917, 74936, 74931, -9999.000, -9999.000, 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3.038, 0.361 75418, 75437, 75432, 0.006, 2.884, 0.247 75438, 75457, 75452, 0.055, 2.730, 0.311 75458, 75477, 75472, 0.055, 2.560, -9999.000 75478, 75497, 75492, 0.071, 3.147, -0.081 75498, 75517, 75512, 0.071, 2.668, 0.601 75518, 75537, 75532, 0.070, 2.188, 0.333 75538, 75557, 75552, 0.070, 2.309, -0.190 75558, 75577, 75572, 0.038, 2.775, 0.435 75578, 75597, 75592, 0.038, 2.635, 0.287 75598, 75617, 75612, 0.032, 2.496, 0.177 75618, 75637, 75632, 0.032, 2.462, 0.173 75638, 75657, 75652, 0.063, 2.670, 0.003 75658, 75677, 75672, 0.063, 2.377, -9999.000 75678, 75697, 75692, 0.085, 2.085, 0.395 75698, 75717, 75712, 0.085, 2.214, 1.274 75718, 75737, 75732, 0.090, 2.477, -9999.000 75738, 75757, 75752, 0.090, 2.601, -9999.000 75758, 75777, 75772, 0.036, 2.725, -9999.000 75778, 75797, 75792, 0.036, 2.055, 0.160 75798, 75817, 75812, 0.028, 2.682, -9999.000 75818, 75837, 75832, 0.028, 2.384, -9999.000 75839, 75858, 75853, 0.034, 2.085, 0.384 75859, 75878, 75873, 0.034, 2.458, 0.028 75879, 75898, 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