42, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2017, 02, 01, 2017, 12, 07 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 23 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #3 -- ANC - KOA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R1 R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 72561, 72580, 72570, -9999.000, 6.798, -9999.000 72581, 72600, 72590, 0.013, 5.379, -9999.000 72601, 72620, 72610, 0.013, 6.918, -9999.000 72621, 72640, 72630, -0.011, 8.466, -9999.000 72641, 72660, 72650, -0.011, 5.054, -9999.000 72661, 72680, 72670, 0.016, 4.239, -9999.000 72681, 72700, 72690, 0.016, 3.363, -9999.000 72701, 72720, 72710, 0.017, 2.486, -9999.000 72721, 72740, 72730, 0.017, 1.942, -9999.000 72741, 72760, 72750, -0.014, 1.445, -9999.000 72761, 72780, 72770, -0.014, 1.519, -9999.000 72781, 72805, 72790, -0.014, -9999.000, 6.503 72927, 72951, 72941, 0.028, -9999.000, -9999.000 72952, 72971, 72961, 0.028, 1.622, 7.578 72972, 72991, 72981, 0.028, 1.491, 6.582 72992, 73011, 73001, 0.030, 1.361, 6.696 73012, 73031, 73021, 0.030, 1.494, 7.593 73032, 73051, 73041, 0.006, 1.538, 4.679 73052, 73071, 73061, 0.006, 1.636, 4.226 73072, 73091, 73081, -0.023, 1.735, 4.201 73092, 73111, 73101, -0.023, 1.546, 2.419 73112, 73131, 73121, -0.022, 1.464, 3.439 73132, 73151, 73141, -0.022, 1.176, 1.336 73152, 73171, 73161, 0.011, 0.888, 1.908 73172, 73191, 73181, 0.011, 1.116, 1.522 73192, 73211, 73201, 0.016, 1.749, 2.050 73212, 73232, 73222, 0.016, 1.584, 0.643 73233, 73252, 73242, 0.034, 1.419, 2.145 73253, 73272, 73262, 0.034, 1.254, 1.469 73273, 73292, 73282, -0.004, 1.090, 1.466 73293, 73312, 73302, -0.004, 0.925, 0.852 73313, 73332, 73322, 0.019, 0.760, 0.521 73333, 73352, 73342, 0.019, 1.363, 0.688 73353, 73372, 73362, -0.013, 1.514, 0.871 73373, 73392, 73382, -0.013, 1.489, 0.678 73393, 73412, 73402, 0.031, 1.465, 0.659 73413, 73432, 73422, 0.031, 1.157, 0.884 73433, 73452, 73442, 0.013, 1.593, 0.450 73453, 73472, 73462, 0.013, 1.499, 0.933 73473, 73492, 73482, 0.037, 1.405, 1.322 73493, 73512, 73502, 0.037, 1.557, 0.712 73513, 73532, 73522, 0.020, 1.856, 0.592 73533, 73552, 73542, 0.020, 1.866, 0.397 73553, 73572, 73562, 0.010, 1.877, 0.010 73573, 73592, 73582, 0.010, 1.739, 0.019 73593, 73612, 73602, 0.057, 2.076, 0.745 73613, 73632, 73622, 0.057, 1.956, 0.412 73633, 73652, 73642, 0.035, 1.836, 0.439 73653, 73672, 73662, 0.035, 1.730, 0.377 73673, 73692, 73682, 0.011, 2.265, 0.564 73693, 73712, 73702, 0.011, 2.199, 0.389 73713, 73732, 73722, 0.034, 2.132, 0.217 73733, 73752, 73742, 0.034, 2.206, 0.115 73753, 73772, 73762, 0.050, 2.455, 0.189 73773, 73792, 73782, 0.050, 2.364, 0.032 73793, 73812, 73802, 0.036, 2.274, 0.853 73813, 73832, 73822, 0.036, 1.968, 0.885 73833, 73852, 73842, 0.063, 2.320, 0.030 73853, 73873, 73863, 0.063, 2.194, 1.053 73874, 73893, 73883, -0.027, 2.070, 0.545 73894, 73913, 73903, -0.027, 2.761, 0.651 73914, 73932, 73922, 0.034, 3.019, 0.408 73933, 73952, 73942, 0.034, 2.717, 1.154 73953, 73972, 73962, -0.005, 2.415, 0.843 73973, 73993, 73982, -0.005, -9999.000, 1.004 74276, 74295, 74285, -9999.000, -9999.000, 0.375 74296, 74315, 74305, 0.021, 2.476, -0.026 74316, 74335, 74325, 0.021, 2.594, 0.481 74336, 74355, 74345, 0.097, 1.475, -0.063 74356, 74375, 74365, 0.097, 1.727, 0.236 74376, 74395, 74385, 0.069, 1.978, 0.244 74396, 74415, 74405, 0.069, 2.271, 0.354 74416, 74435, 74425, 0.120, 2.246, 0.305 74436, 74460, 74445, 0.120, 2.407, 0.193 74556, 74581, 74570, -9999.000, 3.420, -9999.000 74582, 74601, 74591, 0.031, 2.774, -0.388 74602, 74621, 74611, 0.046, 3.600, -9999.000 74622, 74641, 74631, 0.046, 4.100, -9999.000 74642, 74661, 74651, 0.028, 4.603, -0.015 74662, 74681, 74671, 0.028, 3.906, 0.374 74682, 74701, 74691, 0.030, 4.094, 0.282 74702, 74721, 74711, 0.030, 3.886, 0.025 74722, 74741, 74731, 0.031, 3.678, 0.203 74742, 74761, 74751, 0.031, 4.094, -0.398 74762, 74781, 74771, -9999.000, -9999.000, 0.162 74782, 74801, 74791, -9999.000, -9999.000, -0.048 74802, 74821, 74811, -9999.000, -9999.000, -0.006 74822, 74841, 74831, -9999.000, -9999.000, 0.143 74842, 74861, 74851, -9999.000, -9999.000, 0.040 74882, 74901, 74891, -9999.000, -9999.000, -0.282 74902, 74921, 74911, -9999.000, -9999.000, 0.171 74922, 74941, 74931, -9999.000, -9999.000, 0.113 74942, 74961, 74951, -9999.000, -9999.000, 0.198 74982, 75001, 74991, -9999.000, -9999.000, 0.024 75002, 75021, 75011, -9999.000, -9999.000, 0.134 75022, 75041, 75031, -9999.000, -9999.000, 1.070 75042, 75061, 75051, 0.027, 3.974, 0.269 75062, 75081, 75071, 0.027, 4.173, 0.245 75082, 75101, 75091, 0.020, 3.964, 0.388 75102, 75121, 75111, 0.020, 4.183, -9999.000 75122, 75142, 75131, -0.004, 4.403, -9999.000 75143, 75162, 75152, -0.004, 3.872, 0.511 75163, 75182, 75172, 0.078, 4.339, -9999.000 75183, 75202, 75192, 0.078, 4.025, -9999.000 75203, 75222, 75212, -0.024, 3.711, 0.029 75223, 75242, 75232, -0.024, 4.643, 1.527 75243, 75262, 75252, 0.068, 4.091, 0.367 75263, 75282, 75272, 0.068, 4.297, -0.197 75283, 75302, 75292, 0.013, 4.503, -0.285 75303, 75322, 75312, 0.013, 3.862, 0.580 75323, 75342, 75332, 0.072, 4.517, -9999.000 75343, 75362, 75352, 0.072, 4.221, 0.635 75363, 75382, 75372, -0.024, 3.925, -0.004 75383, 75402, 75392, -0.024, 3.944, 0.601 75403, 75422, 75412, 0.007, 4.678, 0.243 75423, 75442, 75432, 0.007, 4.471, 0.127 75443, 75462, 75452, 0.061, 4.265, 0.189 75463, 75482, 75472, 0.061, 3.922, -9999.000 75483, 75502, 75492, 0.078, 4.815, -0.206 75503, 75522, 75512, 0.078, 4.114, 0.471 75523, 75542, 75532, 0.077, 3.413, 0.208 75543, 75562, 75552, 0.077, 3.500, -0.311 75563, 75582, 75572, 0.042, 4.201, 0.308 75583, 75602, 75592, 0.042, 4.009, 0.160 75603, 75622, 75612, 0.035, 3.817, 0.052 75623, 75642, 75632, 0.035, 3.701, 0.044 75643, 75662, 75652, 0.069, 4.012, -0.129 75663, 75682, 75672, 0.069, 3.615, -9999.000 75683, 75702, 75692, 0.093, 3.219, 0.266 75703, 75722, 75712, 0.093, 3.317, 1.143 75723, 75742, 75732, 0.098, 3.711, -9999.000 75743, 75762, 75752, 0.098, 3.919, -9999.000 75763, 75782, 75772, 0.039, 4.126, -9999.000 75783, 75802, 75792, 0.039, 3.071, 0.032 75803, 75822, 75812, 0.030, 4.050, -9999.000 75823, 75843, 75832, 0.030, 3.646, -9999.000 75844, 75863, 75853, 0.037, 3.239, 0.255 75864, 75883, 75873, 0.037, 3.730, -0.097 75884, 75903, 75893, 0.087, 4.463, -0.074 75904, 75923, 75913, 0.087, 4.143, -9999.000 75924, 75943, 75933, 0.043, 3.823, 0.574 75944, 75963, 75953, 0.043, 3.552, -0.199 75964, 75983, 75973, 0.057, 3.501, 0.146 75984, 76003, 75993, 0.057, 3.405, -0.777 76004, 76023, 76013, 0.047, 3.309, -9999.000 76024, 76043, 76033, 0.047, 3.214, 0.341 76044, 76063, 76053, 0.042, 3.631, -0.172 76064, 76083, 76073, 0.042, 3.541, -0.361 76084, 76103, 76093, -0.009, 3.451, 1.104 76104, 76123, 76113, -0.009, 3.028, 0.805 76124, 76143, 76133, 0.038, 2.989, 0.510 76144, 76163, 76153, 0.038, 2.952, -0.263 76164, 76183, 76173, 0.042, 2.915, -0.229 76184, 76203, 76193, 0.042, 2.878, -9999.000 76204, 76223, 76213, 0.036, 3.020, -0.559 76224, 76243, 76233, 0.036, 2.972, 1.034 76244, 76263, 76253, -0.001, 2.923, 1.309 76264, 76283, 76273, -0.001, 2.844, 1.240 76284, 76303, 76293, 0.026, 2.656, 1.342 76304, 76323, 76313, 0.026, 2.407, 0.392 76324, 76343, 76333, 0.028, 2.161, 0.307 76344, 76363, 76353, 0.028, 1.915, 0.852 76364, 76383, 76373, 0.039, 1.992, 1.280 76384, 76403, 76393, 0.039, 2.070, 2.350 76404, 76423, 76413, -0.002, 2.148, 3.217 76424, 76443, 76433, -0.002, 1.758, 4.071 76444, 76463, 76453, 0.001, 2.145, 3.860 76464, 76483, 76473, 0.001, 1.935, 3.207 76484, 76503, 76493, 0.019, 1.726, 3.894 76504, 76524, 76513, 0.019, 1.517, 4.299 76525, 76544, 76534, -0.004, 1.937, 4.530 76545, 76564, 76554, -0.004, 1.660, 4.393 76565, 76584, 76574, -0.001, 1.383, 7.314 76585, 76604, 76594, -0.001, 1.004, 5.838 76605, 76624, 76614, 0.005, 1.687, 5.158 76625, 76644, 76634, 0.005, 1.757, 2.528 76645, 76664, 76654, -0.022, 1.828, 6.608 76665, 76684, 76674, -0.022, 1.899, 3.859 76685, 76704, 76694, 0.001, 1.731, 2.742 76705, 76724, 76714, 0.001, 1.305, 0.094 76725, 76744, 76734, -0.011, 0.879, 1.303 76745, 76764, 76754, -0.011, 0.808, -0.036 76765, 76784, 76774, -0.010, 1.471, 1.928 76785, 76804, 76794, -0.010, 1.441, 1.251 76805, 76824, 76814, -0.016, 1.411, 1.039 76825, 76844, 76834, -0.016, 1.381, 1.940 76845, 76864, 76854, -0.014, 1.183, 0.121 76865, 76884, 76874, -0.014, 1.123, 3.541 76885, 76904, 76894, 0.018, 1.064, 0.379 76905, 76924, 76914, 0.018, 1.670, 1.923 76925, 76944, 76934, -0.010, 1.561, 1.569 76945, 76964, 76954, -0.010, 1.503, 2.926 76965, 76984, 76974, -0.002, 1.446, 1.766 76985, 77004, 76994, -0.002, 1.389, 2.940 77005, 77024, 77014, 0.007, 1.627, 2.782 77025, 77044, 77034, 0.007, 1.799, 5.291 77045, 77064, 77054, -0.004, 1.972, -9999.000 77065, 77084, 77074, -0.004, 2.242, -9999.000 77085, 77105, 77094, -0.023, 1.684, -9999.000 77106, 77125, 77115, -0.023, 1.635, -9999.000 77126, 77144, 77134, -0.005, 1.587, -9999.000 77145, 77164, 77154, -0.005, 1.539, -9999.000 77165, 77184, 77174, 0.025, 1.925, -9999.000 77185, 77205, 77194, 0.025, 2.146, -9999.000 77206, 77225, 77215, 0.013, 2.368, -9999.000 77226, 77245, 77235, 0.013, 1.312, -9999.000 77246, 77265, 77255, -0.003, 1.931, -9999.000 77266, 77285, 77275, -0.003, 1.926, -9999.000 77286, 77305, 77295, -0.005, 1.922, -9999.000 77306, 77325, 77315, -0.005, 1.917, -9999.000 77326, 77345, 77335, 0.001, 2.411, -9999.000 77346, 77365, 77355, 0.001, 2.482, -9999.000 77366, 77385, 77375, -0.033, 2.553, -9999.000 77386, 77405, 77395, -0.033, 1.564, -9999.000 77406, 77425, 77415, 0.032, 1.928, -9999.000 77426, 77450, 77435, 0.032, 1.909, -9999.000 77519, 77546, 77533, 0.033, 1.811, -9999.000 77547, 77569, 77559, 0.033, 4.176, -9999.000 77570, 77589, 77579, -0.001, -9999.000, -9999.000 77590, 77609, 77599, -0.001, -9999.000, -9999.000 77630, 77649, 77639, -9999.000, -9999.000, 4.035 77650, 77669, 77659, -9999.000, -9999.000, 4.876 77670, 77689, 77679, -9999.000, -9999.000, 2.558 77690, 77709, 77699, -9999.000, -9999.000, 1.214 77710, 77729, 77719, -9999.000, -9999.000, 1.035 77730, 77749, 77739, -9999.000, -9999.000, 0.213 77750, 77769, 77759, -9999.000, -9999.000, 0.833 77770, 77789, 77779, -9999.000, -9999.000, 1.120 77790, 77809, 77799, -9999.000, -9999.000, -0.191 77810, 77829, 77819, 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78310, 78300, 0.005, 4.464, 0.402 78311, 78330, 78320, 0.005, 4.049, 1.057 78331, 78350, 78340, 0.060, 3.632, 0.209 78351, 78370, 78360, 0.060, 3.822, -0.155 78371, 78390, 78380, 0.024, 4.727, 0.026 78391, 78410, 78400, 0.024, 4.552, 0.280 78411, 78430, 78420, -0.006, 4.375, -0.034 78431, 78450, 78440, -0.006, 4.060, 0.306 78451, 78470, 78460, 0.010, 3.617, 0.400 78471, 78490, 78480, 0.010, 3.668, 0.190 78491, 78510, 78500, 0.062, 3.719, 0.018 78511, 78530, 78520, 0.062, 4.384, -0.036 78531, 78550, 78540, 0.058, 4.034, -0.409 78551, 78570, 78560, 0.058, 4.363, -0.593 78571, 78590, 78580, 0.041, 4.692, -0.044 78591, 78610, 78600, 0.041, 4.495, 0.287 78611, 78630, 78620, 0.066, 4.114, 0.449 78631, 78650, 78640, 0.066, 3.859, 0.157 78651, 78670, 78660, 0.014, 3.604, -0.019 78671, 78690, 78680, 0.014, 4.542, -0.207 78691, 78710, 78700, 0.040, 4.423, -0.063 78711, 78730, 78720, 0.040, 4.444, 0.029 78731, 78750, 78740, 0.050, 4.465, -0.315 78751, 78770, 78760, 0.050, 4.106, 0.341 78771, 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