47, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2017, 01, 26, 2018, 10, 25 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 29 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #1 -- PMD - PMD ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R3 R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 61870, 61889, 61880, -9999.000, -9999.000 61890, 61909, 61900, -9999.000, -9999.000 61910, 61929, 61920, -9999.000, -9999.000 61930, 61949, 61940, -9999.000, -9999.000 61950, 61969, 61960, -9999.000, -9999.000 61970, 61989, 61980, -9999.000, -9999.000 61990, 62009, 62000, -9999.000, -9999.000 62010, 62029, 62020, -9999.000, -9999.000 62030, 62049, 62040, -9999.000, 7.694 62050, 62069, 62060, -9999.000, 8.024 62070, 62089, 62080, -9999.000, 10.038 62090, 62109, 62100, -9999.000, 12.052 62110, 62129, 62120, 0.135, 8.435 62130, 62149, 62140, 0.135, 7.396 62150, 62169, 62160, 0.096, 9.485 62170, 62189, 62180, 0.080, 11.574 62190, 62209, 62200, 0.080, 13.457 62210, 62229, 62220, 0.080, 13.689 62230, 62249, 62240, 0.073, 14.641 62250, 62269, 62260, 0.073, 15.593 62270, 62289, 62280, 0.030, 13.513 62290, 62309, 62300, 0.019, 11.787 62310, 62329, 62320, 0.019, 10.079 62330, 62349, 62340, 0.019, 8.370 62350, 62369, 62360, 0.026, 6.800 62370, 62389, 62380, 0.027, 6.648 62390, 62409, 62400, 0.027, 5.874 62410, 62429, 62420, 0.027, 5.100 62431, 62450, 62441, 0.042, 8.024 62451, 62470, 62461, 0.070, 8.918 62471, 62490, 62481, 0.070, 8.880 62491, 62510, 62501, 0.020, 8.842 62511, 62530, 62521, 0.020, 11.419 62531, 62550, 62541, 0.032, 10.182 62551, 62570, 62561, 0.032, 10.636 62571, 62590, 62581, 0.072, 11.094 62591, 62610, 62601, 0.072, 10.710 62611, 62630, 62621, 0.072, 11.219 62631, 62650, 62641, 0.010, 9.853 62651, 62670, 62661, 0.045, 8.480 62671, 62690, 62681, 0.045, 8.129 62691, 62710, 62701, 0.045, 7.157 62711, 62730, 62721, 0.056, 7.387 62731, 62750, 62741, 0.064, 7.617 62751, 62770, 62761, 0.064, 7.130 62771, 62790, 62781, 0.068, 7.427 62791, 62810, 62801, 0.068, 6.782 62811, 62830, 62821, 0.068, 6.138 62831, 62850, 62841, 0.040, 6.145 62851, 62870, 62861, 0.040, 7.386 62871, 62890, 62881, 0.020, 7.780 62891, 62910, 62901, 0.020, 8.174 62911, 62930, 62921, 0.067, 6.122 62931, 62950, 62941, 0.067, 6.714 62951, 62970, 62961, 0.063, 6.291 62971, 62990, 62981, 0.063, 5.872 62991, 63010, 63001, 0.114, 6.298 63011, 63030, 63021, 0.064, 8.392 63031, 63050, 63041, 0.064, 7.516 63051, 63070, 63061, 0.064, 6.639 63072, 63091, 63082, 0.057, 7.188 63092, 63111, 63102, 0.040, 6.672 63112, 63131, 63122, 0.040, 6.394 63132, 63151, 63142, 0.040, 6.116 63152, 63171, 63162, 0.095, 6.235 63172, 63191, 63182, 0.095, 5.760 63192, 63211, 63202, 0.087, 6.614 63212, 63231, 63222, 0.101, 7.472 63232, 63251, 63242, 0.101, 6.232 63252, 63271, 63262, 0.101, 6.782 63272, 63291, 63282, 0.102, 6.238 63292, 63311, 63302, 0.101, 5.694 63312, 63331, 63322, 0.101, 4.879 63332, 63351, 63342, 0.101, 4.729 63352, 63371, 63362, 0.135, 4.459 63372, 63391, 63382, 0.135, 4.188 63392, 63411, 63402, 0.135, 4.057 63412, 63431, 63422, 0.135, 3.954 63432, 63451, 63442, 0.120, 3.853 63452, 63471, 63462, 0.129, 3.753 63472, 63491, 63482, 0.129, 3.803 63492, 63511, 63502, 0.160, 3.855 63512, 63531, 63522, 0.160, 3.714 63532, 63551, 63542, 0.143, 3.573 63552, 63571, 63562, 0.143, 3.564 63572, 63591, 63582, 0.126, 3.359 63592, 63611, 63602, 0.126, 2.952 63612, 63631, 63622, 0.126, 2.541 63632, 63651, 63642, 0.137, 2.807 63652, 63671, 63662, 0.165, 3.251 63672, 63691, 63682, 0.165, 3.247 63693, 63712, 63703, 0.112, 3.244 63713, 63732, 63723, 0.112, 3.204 63732, 63751, 63742, 0.112, 2.663 63753, 63772, 63763, 0.160, 2.456 63773, 63792, 63783, 0.173, 2.252 63793, 63812, 63803, 0.173, 2.161 63813, 63832, 63823, 0.173, 2.998 63833, 63852, 63843, 0.173, 3.065 63853, 63872, 63863, 0.173, 3.132 63873, 63892, 63883, 0.184, 2.842 63893, 63912, 63903, 0.188, 2.984 63913, 63932, 63923, 0.188, 3.211 63933, 63952, 63943, 0.184, 3.437 63953, 63972, 63963, 0.184, 3.365 63973, 63992, 63983, 0.184, 3.466 63993, 64012, 64003, 0.146, 3.585 64013, 64032, 64023, 0.192, 3.704 64033, 64052, 64043, 0.192, 4.315 64053, 64072, 64063, 0.192, 3.914 64073, 64092, 64083, 0.192, 3.381 64093, 64112, 64103, 0.192, 2.853 64113, 64132, 64123, 0.244, 3.847 64133, 64152, 64143, 0.218, 4.529 64153, 64172, 64163, 0.218, 4.400 64173, 64192, 64183, 0.218, 4.271 64193, 64212, 64203, 0.192, 4.944 64213, 64232, 64223, 0.192, 5.025 64233, 64252, 64243, 0.212, 5.112 64253, 64272, 64263, 0.175, 5.198 64273, 64292, 64283, 0.175, 4.406 64293, 64312, 64303, 0.204, 6.030 64313, 64332, 64323, 0.204, 5.736 64333, 64352, 64343, 0.236, 5.442 64353, 64372, 64363, 0.236, 5.636 64374, 64393, 64384, 0.229, 6.282 64394, 64413, 64404, 0.229, 6.244 64414, 64433, 64424, 0.237, 6.206 64434, 64453, 64444, 0.237, 6.767 64454, 64473, 64464, 0.237, 7.407 64474, 64493, 64484, 0.232, 7.031 64494, 64513, 64504, 0.207, 6.654 64514, 64533, 64524, 0.207, 6.586 64534, 64553, 64544, 0.207, 7.255 64554, 64573, 64564, 0.223, 7.901 64574, 64593, 64584, 0.223, 8.547 64594, 64613, 64604, 0.223, 8.640 64742, 64761, 64752, 0.210, 11.501 64762, 64781, 64772, 0.210, 12.042 64782, 64801, 64792, 0.210, 12.578 64802, 64821, 64812, 0.210, 10.895 64822, 64841, 64832, 0.210, 11.452 64842, 64861, 64852, 0.210, 11.425 64862, 64881, 64872, 0.210, 11.398 64882, 64901, 64892, 0.195, 11.372 64902, 64921, 64912, 0.195, 14.129 64922, 64941, 64932, 0.203, 14.058 64942, 64961, 64952, 0.189, 13.987 64962, 64981, 64972, 0.189, 12.588 64982, 65001, 64992, 0.189, 12.644 65002, 65021, 65012, 0.176, 12.435 65022, 65041, 65032, 0.176, 12.225 65042, 65061, 65052, 0.182, 12.015 65062, 65081, 65072, 0.187, 12.190 65082, 65101, 65092, 0.187, 13.064 65102, 65121, 65112, 0.200, 13.937 65122, 65141, 65132, 0.200, 12.690 65142, 65161, 65152, 0.200, 13.110 65162, 65181, 65172, 0.170, 12.700 65183, 65202, 65193, 0.170, 12.288 65203, 65222, 65213, 0.135, 11.876 65223, 65242, 65233, 0.105, 14.530 65243, 65262, 65253, 0.105, 14.280 65263, 65282, 65273, 0.090, 14.029 65283, 65302, 65293, 0.090, 14.268 65303, 65322, 65313, 0.093, 14.229 65323, 65342, 65333, 0.093, 14.328 65343, 65362, 65353, 0.093, 14.426 65363, 65382, 65373, 0.109, 14.525 65383, 65402, 65393, 0.098, 15.815 65403, 65422, 65413, 0.098, 16.281 65423, 65442, 65433, 0.151, 16.748 65443, 65462, 65453, 0.151, 16.504 65463, 65482, 65473, 0.151, 14.876 65483, 65502, 65493, 0.113, 14.683 65503, 65522, 65513, 0.113, 14.491 65523, 65542, 65533, 0.122, 16.426 65543, 65562, 65553, 0.122, 15.938 65563, 65582, 65573, 0.112, 15.667 65583, 65602, 65593, 0.091, 15.396 65603, 65622, 65613, 0.091, 14.976 65623, 65642, 65633, 0.091, 13.576 65643, 65662, 65653, 0.152, 13.777 65663, 65682, 65673, 0.152, 13.977 65683, 65702, 65693, 0.125, 14.178 65703, 65722, 65713, 0.134, 13.712 65723, 65742, 65733, 0.134, 14.436 65743, 65762, 65753, 0.134, 15.161 65763, 65782, 65773, 0.122, 16.204 65783, 65802, 65793, 0.109, 14.955 65803, 65822, 65813, 0.109, 14.523 65823, 65842, 65833, 0.108, 14.090 65843, 65862, 65853, 0.108, 13.658 65863, 65882, 65873, 0.108, 14.183 65883, 65902, 65893, 0.147, 14.430 65904, 65923, 65914, 0.164, 14.679 65924, 65943, 65934, 0.164, 15.716 65944, 65963, 65954, 0.164, 16.804 65964, 65983, 65974, 0.161, 16.108 65984, 66003, 65994, 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66583, 66574, 0.042, 16.127 66584, 66603, 66594, 0.042, 14.940 66605, 66624, 66615, 0.020, 15.562 66625, 66644, 66635, 0.020, 16.180 66645, 66664, 66655, 0.102, 16.799 66665, 66684, 66675, -9999.000, 17.940 66685, 66704, 66695, -9999.000, 17.701 66705, 66724, 66715, -9999.000, 17.462 66725, 66744, 66735, 0.179, 14.497 66745, 66764, 66755, 0.236, 13.804 66765, 66784, 66775, 0.236, 15.065 66785, 66804, 66795, 0.152, 16.326 66805, 66824, 66815, 0.152, 17.586 66825, 66844, 66835, 0.152, 16.717 66845, 66864, 66855, 0.104, 17.607 66865, 66884, 66875, 0.104, 18.502 66885, 66904, 66895, 0.186, 14.102 66905, 66924, 66915, 0.186, 15.318 66925, 66944, 66935, 0.121, 15.834 66945, 66964, 66955, 0.150, 16.350 66965, 66984, 66975, 0.150, 16.866 66985, 67004, 66995, 0.118, 16.630 67005, 67024, 67015, 0.118, 17.690 67025, 67044, 67035, 0.133, 18.761 67045, 67064, 67055, 0.133, 15.075 67065, 67084, 67075, 0.172, 17.131 67085, 67104, 67095, 0.172, 16.783 67105, 67124, 67115, 0.172, 16.435 67125, 67144, 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