43, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2016, 08, 20, 2018, 02, 16 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 24 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #9 -- TER - SFJ ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. ATHOS is calibrated with the new OH scavenging inlet. Differences with previous version due to improved calibration methods. OH & HO2 uncertainty ~1.32, 2 sigma confidence. Data in dense clouds is noisy, and is removed. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO works for conditions up to ambient NO ~20 ppbv; data are not recoverd for some low altitudes. REVISION: R2 R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 32930, 32959, 32944, -9999.000, -9999.000, 2.197 32960, 32989, 32974, -9999.000, -9999.000, 1.189 32990, 33019, 33004, -9999.000, -9999.000, 0.798 33020, 33049, 33034, -9999.000, 16.114, 0.750 33050, 33079, 33064, 0.284, 15.226, 0.651 33081, 33110, 33095, 0.284, 16.347, 1.866 33111, 33140, 33125, 0.154, 17.133, 1.604 33141, 33170, 33155, 0.154, 17.917, 1.733 33171, 33200, 33185, 0.376, 16.465, 2.301 33201, 33230, 33215, 0.376, 15.012, 4.096 33231, 33260, 33245, 0.261, 13.564, 2.830 33261, 33290, 33275, 0.261, 12.097, 2.530 33291, 33320, 33305, 0.314, 13.046, 2.198 33321, 33350, 33335, 0.314, 12.088, 1.622 33351, 33380, 33365, 0.287, 12.504, 1.445 33381, 33410, 33395, 0.287, 12.916, 2.887 33411, 33440, 33425, 0.373, 13.395, 1.086 33441, 33470, 33455, 0.373, 12.472, 1.623 33471, 33500, 33485, 0.370, 11.763, 1.892 33502, 33531, 33516, 0.370, 11.049, 1.867 33532, 33561, 33546, 0.296, 13.507, 2.316 33562, 33591, 33576, 0.296, 13.057, 1.625 33592, 33621, 33606, 0.445, 12.644, 2.508 33622, 33651, 33636, 0.445, 12.236, 1.049 33652, 33681, 33666, 0.551, 11.572, 1.757 33682, 33711, 33696, 0.551, 10.328, 1.041 33712, 33741, 33726, 0.377, 9.653, 0.992 33742, 33771, 33756, 0.377, 8.974, 1.714 33772, 33801, 33786, 0.388, 9.123, 1.683 33802, 33831, 33816, 0.388, 8.522, 1.320 33832, 33861, 33846, 0.328, 8.438, 1.611 33862, 33891, 33876, 0.328, 8.355, 1.290 33893, 33922, 33907, 0.227, 9.912, 1.022 33923, 33952, 33937, 0.227, 8.554, 1.533 33953, 33982, 33967, 0.258, 7.614, 1.049 33983, 34012, 33997, 0.258, 6.668, -9999.000 34113, 34142, 34127, 0.192, 8.645, -9999.000 34143, 34172, 34157, 0.192, 8.890, 0.753 34173, 34202, 34187, 0.259, 8.106, 0.686 34203, 34232, 34217, 0.259, 7.320, 1.253 34234, 34263, 34248, 0.381, 8.216, 1.251 34264, 34293, 34278, 0.381, 9.101, 1.432 34294, 34323, 34308, 0.258, 8.622, 0.260 34324, 34353, 34338, 0.258, 8.142, 0.567 34354, 34383, 34368, 0.296, 7.983, 0.704 34384, 34413, 34398, 0.296, 8.406, 1.097 34414, 34443, 34428, 0.249, 8.547, 0.332 34444, 34473, 34458, 0.249, 8.689, 0.525 34474, 34503, 34488, 0.317, 7.942, 1.308 34504, 34533, 34518, 0.317, 8.870, 0.272 34534, 34563, 34548, 0.338, 8.664, 0.276 34564, 34593, 34578, 0.338, 8.459, 0.866 34594, 34623, 34608, 0.327, 8.815, 0.603 34625, 34654, 34639, 0.327, 8.967, 0.622 34655, 34684, 34669, 0.245, 8.014, -0.026 34685, 34714, 34699, 0.245, 7.061, 0.894 34715, 34744, 34729, 0.244, 7.711, 1.052 34745, 34774, 34759, 0.244, 8.476, 0.349 34775, 34804, 34789, 0.284, 8.306, 0.899 34805, 34834, 34819, 0.284, 8.134, 0.758 34835, 34864, 34849, 0.263, 8.174, -9999.000 34865, 34894, 34879, 0.263, 7.585, 0.886 34895, 34924, 34909, 0.234, 7.300, 0.648 34925, 34954, 34939, 0.234, 7.015, 0.584 34955, 34984, 34969, 0.282, 8.202, 0.915 34985, 35014, 34999, 0.282, 8.074, 0.287 35015, 35044, 35029, 0.255, 7.769, 0.773 35046, 35075, 35060, 0.255, 7.461, 0.436 35076, 35105, 35090, 0.186, 7.850, 0.191 35106, 35135, 35120, 0.186, 10.059, -0.092 35136, 35165, 35150, 0.309, 11.227, 0.716 35166, 35195, 35180, 0.309, 12.391, 0.693 35196, 35225, 35210, 0.295, 14.804, 0.808 35226, 35255, 35240, 0.295, 14.593, 1.108 35256, 35285, 35270, 0.350, 12.869, 0.609 35286, 35315, 35300, 0.350, 11.132, 0.621 35316, 35345, 35330, 0.247, 11.287, 0.853 35346, 35375, 35360, 0.247, 11.746, 0.565 35376, 35405, 35390, 0.305, 11.544, 0.247 35406, 35435, 35420, 0.305, 11.343, 0.472 35436, 35465, 35450, 0.256, 13.546, 0.741 35467, 35496, 35481, 0.256, 15.032, 1.669 35497, 35526, 35511, 0.318, 14.324, 1.952 35527, 35556, 35541, 0.318, 13.612, 1.483 35557, 35586, 35571, 0.346, 14.477, 0.637 35587, 35616, 35601, 0.346, 15.927, 0.898 35617, 35646, 35631, 0.284, 14.100, 1.354 35647, 35676, 35661, 0.284, 12.274, 0.914 35677, 35706, 35691, 0.217, 13.146, 0.629 35707, 35736, 35721, 0.217, 12.032, 3.442 35737, 35766, 35751, 0.247, 11.348, 2.432 35767, 35796, 35781, 0.247, 10.659, 2.436 35797, 35826, 35811, 0.031, 10.185, 1.919 35827, 35856, 35841, 0.031, 12.592, 0.776 35857, 35886, 35871, 0.055, 10.633, -9999.000 35887, 35916, 35901, 0.055, 8.680, 1.345 35918, 35947, 35932, 0.055, 9.512, -9999.000 36055, 36084, 36069, -9999.000, 10.171, -9999.000 36141, 36170, 36155, 0.085, 11.024, -9999.000 36171, 36200, 36185, 0.085, 11.324, 1.208 36201, 36230, 36215, 0.089, 12.273, 1.739 36231, 36260, 36245, 0.089, 11.362, 1.146 36262, 36291, 36276, 0.061, 11.835, -9999.000 36292, 36321, 36306, 0.061, 12.306, 1.220 36322, 36351, 36336, 0.124, 9.731, -9999.000 36352, 36381, 36366, 0.124, 12.886, -9999.000 36382, 36411, 36396, 0.027, -9999.000, 2.183 36412, 36441, 36426, 0.027, -9999.000, 2.133 36442, 36471, 36456, -9999.000, -9999.000, 2.498 36472, 36501, 36486, -9999.000, -9999.000, 1.707 36502, 36531, 36516, 0.215, -9999.000, 1.097 36532, 36561, 36546, 0.215, -9999.000, 1.954 36562, 36591, 36576, -9999.000, -9999.000, 2.522 36592, 36621, 36606, -9999.000, -9999.000, 2.945 36622, 36651, 36636, 0.602, -9999.000, 0.597 36652, 36681, 36666, 0.602, -9999.000, 1.958 36682, 36711, 36696, 0.779, -9999.000, 0.633 36712, 36741, 36726, 0.779, -9999.000, 1.321 36743, 36772, 36757, 0.729, 21.191, 0.454 36773, 36802, 36787, 0.729, 18.895, 1.182 36803, 36832, 36817, 0.595, 21.035, 1.382 36833, 36862, 36847, 0.595, 18.138, 1.441 36863, 36892, 36877, 0.803, 18.191, 1.090 36893, 36922, 36907, 0.803, 18.244, 0.147 36923, 36952, 36937, 0.841, 16.836, 0.292 36953, 36982, 36967, 0.841, 18.342, 0.671 36983, 37012, 36997, 0.655, 17.685, 1.396 37013, 37042, 37027, 0.655, 17.025, 0.686 37043, 37072, 37057, 0.667, 17.703, 1.289 37073, 37102, 37087, 0.667, 14.953, 0.862 37103, 37132, 37117, 0.604, 13.828, 0.820 37133, 37162, 37147, 0.604, 12.699, 0.695 37164, 37193, 37178, 0.544, 15.198, 0.361 37194, 37223, 37208, 0.544, 14.400, 1.379 37224, 37253, 37238, 0.654, 15.016, 0.384 37254, 37283, 37268, 0.654, 15.632, 0.996 37284, 37313, 37298, 0.631, 14.144, 0.597 37314, 37343, 37328, 0.631, -9999.000, -0.114 37344, 37373, 37358, -9999.000, -9999.000, 0.937 37374, 37403, 37388, -9999.000, -9999.000, 1.290 37404, 37433, 37418, 0.700, 13.438, 1.170 37434, 37463, 37448, 0.700, 14.322, 0.181 37464, 37493, 37478, 0.879, 13.527, 0.806 37494, 37523, 37508, 0.879, 12.737, 0.484 37524, 37553, 37538, 0.762, 12.468, 0.960 37554, 37583, 37568, 0.762, 11.423, 1.013 37585, 37614, 37599, 0.823, 11.990, -9999.000 37615, 37644, 37629, 0.823, 12.554, 0.165 37645, 37674, 37659, 0.906, 11.653, 0.276 37675, 37704, 37689, 0.906, 11.417, 0.186 37705, 37734, 37719, 0.842, 11.087, 0.099 37735, 37764, 37749, 0.842, 10.753, -9999.000 37765, 37794, 37779, 0.731, 12.976, 0.063 37795, 37824, 37809, 0.731, 13.456, 0.238 37825, 37854, 37839, 0.731, 13.793, -9999.000 37944, 37973, 37958, 0.701, 15.121, -9999.000 37974, 38003, 37988, 0.701, 15.571, -0.062 38004, 38033, 38018, 0.701, 18.824, -0.205 38034, 38063, 38048, 0.597, 16.263, 0.725 38065, 38094, 38079, 0.597, 13.702, 0.250 38095, 38124, 38109, 0.788, 18.974, 0.813 38125, 38154, 38139, 0.788, 18.779, 0.644 38155, 38184, 38169, 0.687, 17.660, 0.530 38185, 38214, 38199, 0.687, 16.541, 0.142 38215, 38244, 38229, -9999.000, -9999.000, 0.735 38245, 38274, 38259, 0.446, 16.671, 0.802 38275, 38304, 38289, 0.683, 17.472, -0.344 38305, 38334, 38319, 0.683, 18.274, 1.544 38335, 38364, 38349, 0.580, 20.056, 0.976 38365, 38394, 38379, 0.580, 21.238, 0.337 38395, 38424, 38409, 0.413, 17.424, 0.537 38425, 38454, 38439, 0.413, 13.609, 0.550 38455, 38484, 38469, -9999.000, -9999.000, 0.522 38515, 38544, 38529, -9999.000, -9999.000, 1.873 38546, 38575, 38560, -9999.000, -9999.000, 1.299 38576, 38605, 38590, -9999.000, -9999.000, -0.114 38606, 38635, 38620, -9999.000, -9999.000, 1.211 38636, 38665, 38650, 0.213, -9999.000, 0.973 38666, 38695, 38680, 0.213, -9999.000, -9999.000 38696, 38725, 38710, -9999.000, -9999.000, 2.898 38726, 38755, 38740, -9999.000, -9999.000, 2.229 38756, 38785, 38770, -9999.000, -9999.000, 1.832 38786, 38815, 38800, -9999.000, 15.587, 1.430 38816, 38845, 38830, 0.212, 17.578, 2.346 38847, 38876, 38861, 0.212, 18.918, 1.692 38877, 38906, 38891, 0.181, 18.111, 2.413 38907, 38936, 38921, 0.181, 17.304, 0.675 38937, 38966, 38951, 0.272, 18.444, 2.121 38967, 38996, 38981, 0.272, 19.751, 2.239 38997, 39026, 39011, 0.280, 22.096, 1.474 39027, 39056, 39041, 0.280, 24.440, -9999.000 39057, 39086, 39071, 0.357, 21.526, 1.341 39087, 39116, 39101, 0.357, 21.817, 2.153 39117, 39146, 39131, 0.280, 20.868, 0.806 39147, 39176, 39161, 0.280, 19.916, 0.915 39177, 39206, 39191, 0.168, 18.618, 0.483 39207, 39236, 39221, 0.168, 17.277, 1.121 39238, 39267, 39252, 0.289, 16.575, 1.214 39268, 39297, 39282, 0.289, 15.878, 1.306 39298, 39327, 39312, 0.437, 16.383, 0.853 39328, 39357, 39342, 0.437, 17.033, 0.727 39358, 39387, 39372, 0.357, 14.454, 0.096 39388, 39417, 39402, 0.357, 11.866, 0.507 39418, 39447, 39432, 0.265, 14.052, 0.253 39448, 39477, 39462, 0.265, 14.380, 0.675 39478, 39507, 39492, 0.315, 14.311, 0.799 39508, 39537, 39522, 0.315, 14.243, 0.424 39538, 39567, 39552, 0.313, 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