48, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2016, 08, 12, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 30 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #6 -- CHC - PUQ ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R4 R4: Final Data (see OTHER_COMMENTS) R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 80113, 80142, 80128, -9999.000, -9999.000 80143, 80172, 80158, -9999.000, -9999.000 80173, 80202, 80188, -9999.000, -9999.000 80203, 80232, 80218, -9999.000, -9999.000 80234, 80263, 80249, -9999.000, 1.707 80264, 80293, 80279, -9999.000, 1.596 80294, 80323, 80309, -9999.000, -0.057 80324, 80353, 80339, -9999.000, 2.217 80354, 80383, 80369, -9999.000, 4.462 80384, 80413, 80399, -9999.000, 3.940 80414, 80443, 80429, -9999.000, -9999.000 80444, 80473, 80459, -9999.000, -9999.000 80474, 80503, 80489, -9999.000, 0.956 80504, 80533, 80519, -9999.000, 1.283 80534, 80563, 80549, -9999.000, 1.608 80564, 80593, 80579, 0.051, 1.936 80594, 80623, 80609, 0.051, 2.262 80624, 80653, 80639, 0.051, 3.917 80655, 80684, 80670, -0.000, 3.815 80684, 80713, 80699, 0.061, 3.300 80714, 80743, 80729, 0.061, 2.786 80745, 80774, 80760, 0.044, 2.581 80775, 80804, 80790, 0.044, 2.069 80805, 80834, 80820, 0.040, 1.924 80835, 80864, 80850, 0.040, 1.779 80865, 80894, 80880, 0.040, 2.013 80895, 80924, 80910, 0.032, 1.477 80925, 80954, 80940, 0.033, 1.734 80955, 80984, 80970, 0.033, 1.991 80985, 81014, 81000, 0.031, 1.634 81015, 81044, 81030, 0.031, 1.801 81045, 81074, 81060, 0.031, 1.998 81075, 81104, 81090, 0.018, 2.195 81105, 81134, 81120, 0.018, 1.926 81135, 81164, 81150, -0.002, 1.884 81165, 81194, 81180, -0.002, 1.920 81195, 81224, 81210, 0.050, 1.956 81226, 81255, 81241, 0.043, 2.698 81256, 81285, 81271, 0.043, 2.514 81286, 81315, 81301, 0.043, 2.026 81316, 81345, 81331, 0.077, 1.535 81346, 81375, 81361, 0.077, 3.846 81376, 81405, 81391, 0.068, 2.404 81406, 81435, 81421, 0.033, 2.634 81436, 81465, 81451, 0.033, 2.861 81466, 81495, 81481, 0.067, 2.734 81496, 81525, 81511, 0.067, 2.973 81526, 81555, 81541, 0.067, 2.781 81557, 81586, 81572, 0.043, 2.588 81587, 81616, 81602, 0.043, 2.438 81617, 81646, 81632, 0.064, 2.562 81647, 81676, 81662, 0.056, 2.476 81677, 81706, 81692, 0.056, 2.390 81707, 81736, 81722, 0.064, 2.615 81737, 81766, 81752, 0.064, 1.798 81767, 81796, 81782, 0.064, 1.641 81797, 81826, 81812, 0.070, 1.484 81827, 81856, 81842, 0.070, 2.270 81857, 81886, 81872, 0.071, 2.455 81887, 81916, 81902, 0.071, 2.144 81918, 81947, 81933, 0.046, 1.834 81948, 81977, 81963, 0.065, 2.386 81978, 82007, 81993, 0.065, 2.125 82008, 82037, 82023, 0.065, 2.128 82038, 82067, 82053, 0.070, 2.132 82068, 82097, 82083, 0.070, 1.853 82098, 82127, 82113, 0.054, 1.960 82128, 82157, 82143, 0.078, 2.049 82158, 82187, 82173, 0.078, 2.138 82188, 82217, 82203, 0.048, 2.347 82218, 82247, 82233, 0.048, 2.298 82248, 82277, 82263, 0.048, 2.526 82278, 82307, 82293, 0.070, 2.756 82308, 82337, 82323, 0.070, 2.240 82338, 82367, 82353, 0.040, 2.700 82369, 82398, 82384, 0.034, 2.533 82399, 82428, 82414, 0.034, 2.368 82429, 82458, 82444, 0.034, 2.773 82459, 82488, 82474, 0.055, 2.582 82489, 82518, 82504, 0.055, 2.293 82519, 82548, 82534, 0.032, 2.001 82549, 82578, 82564, 0.036, 2.385 82579, 82608, 82594, 0.036, 2.567 82609, 82638, 82624, 0.027, 2.791 82639, 82668, 82654, 0.027, 3.012 82669, 82698, 82684, 0.012, 3.058 82699, 82728, 82714, 0.012, 3.370 82729, 82758, 82744, 0.012, 2.677 82760, 82789, 82775, 0.038, 1.976 82789, 82818, 82804, 0.038, 3.068 82819, 82848, 82834, 0.035, 2.596 82850, 82879, 82865, 0.009, 2.701 82880, 82909, 82895, 0.009, 2.806 82910, 82939, 82925, 0.009, 4.368 82940, 82969, 82955, -0.002, 3.433 82970, 82999, 82985, -0.002, 3.691 83000, 83029, 83015, 0.048, 3.950 83030, 83059, 83045, 0.041, 3.464 83060, 83089, 83075, 0.041, 4.045 83090, 83119, 83105, 0.058, 4.450 83120, 83149, 83135, 0.058, 4.852 83150, 83179, 83165, 0.058, 5.572 83181, 83210, 83196, 0.024, 4.677 83211, 83240, 83226, 0.024, 4.154 83241, 83270, 83256, 0.024, 3.631 83271, 83300, 83286, 0.036, 3.819 83301, 83330, 83316, 0.036, 4.667 83331, 83360, 83346, 0.036, 3.667 83361, 83390, 83376, 0.045, 2.667 83501, 83530, 83516, 0.009, 4.110 83531, 83560, 83546, 0.009, 3.297 83561, 83590, 83576, 0.009, 3.180 83591, 83620, 83606, 0.048, 3.062 83621, 83650, 83636, 0.013, 3.357 83651, 83680, 83666, 0.013, 4.133 83681, 83710, 83696, -9999.000, -9999.000 83711, 83740, 83726, -9999.000, -9999.000 83741, 83770, 83756, -9999.000, -9999.000 83772, 83801, 83787, -9999.000, -9999.000 83802, 83831, 83817, -9999.000, -9999.000 83832, 83861, 83847, -9999.000, -9999.000 83862, 83891, 83877, -9999.000, -9999.000 83892, 83921, 83907, -9999.000, -9999.000 83922, 83951, 83937, -9999.000, -9999.000 83952, 83981, 83967, -9999.000, -9999.000 83982, 84011, 83997, -9999.000, -9999.000 84012, 84041, 84027, -9999.000, -9999.000 84042, 84071, 84057, -9999.000, -9999.000 84072, 84101, 84087, -9999.000, -9999.000 84102, 84131, 84117, -9999.000, -9999.000 84132, 84161, 84147, -9999.000, -9999.000 84163, 84192, 84178, -9999.000, -9999.000 84193, 84222, 84208, -9999.000, -9999.000 84223, 84252, 84238, -9999.000, -9999.000 84253, 84282, 84268, -9999.000, -9999.000 84283, 84312, 84298, -9999.000, -9999.000 84313, 84342, 84328, -9999.000, -9999.000 84343, 84372, 84358, -9999.000, -9999.000 84373, 84402, 84388, -9999.000, -9999.000 84403, 84432, 84418, -9999.000, -9999.000 84433, 84462, 84448, -9999.000, -9999.000 84463, 84492, 84478, -9999.000, -9999.000 84493, 84522, 84508, -9999.000, -9999.000 84523, 84552, 84538, -9999.000, -9999.000 84553, 84582, 84568, -9999.000, -9999.000 84583, 84612, 84598, -9999.000, -9999.000 84613, 84642, 84628, -9999.000, -9999.000 84644, 84673, 84659, -9999.000, -9999.000 84674, 84703, 84689, -9999.000, -9999.000 84704, 84733, 84719, -9999.000, -9999.000 84734, 84763, 84749, -9999.000, -9999.000 84764, 84793, 84779, -9999.000, -9999.000 84794, 84823, 84809, -9999.000, -9999.000 84824, 84853, 84839, -9999.000, -9999.000 84854, 84883, 84869, -9999.000, -9999.000 84884, 84913, 84899, -9999.000, -9999.000 84914, 84943, 84929, -9999.000, -9999.000 84944, 84973, 84959, -9999.000, -9999.000 84974, 85003, 84989, -9999.000, -9999.000 85004, 85033, 85019, -9999.000, -9999.000 85034, 85063, 85049, -9999.000, -9999.000 85065, 85094, 85080, 0.029, 4.120 85095, 85124, 85110, 0.029, 3.613 85125, 85154, 85140, 0.029, 3.444 85155, 85184, 85170, 0.046, 3.273 85185, 85214, 85200, 0.046, 3.473 85215, 85244, 85230, 0.052, 3.599 85245, 85274, 85260, 0.026, 3.363 85275, 85304, 85290, 0.026, 3.127 85305, 85334, 85320, 0.052, 3.760 85335, 85364, 85350, 0.052, 3.718 85365, 85394, 85380, 0.052, 3.727 85395, 85424, 85410, 0.032, 3.737 85425, 85454, 85440, 0.032, 4.191 85456, 85485, 85471, 0.047, 3.727 85486, 85515, 85501, 0.042, 3.652 85516, 85545, 85531, 0.042, 3.578 85546, 85575, 85561, 0.042, 3.381 85576, 85605, 85591, 0.035, 3.088 85606, 85635, 85621, 0.035, 3.176 85636, 85665, 85651, 0.061, 3.265 85666, 85695, 85681, 0.038, 3.299 85696, 85725, 85711, 0.038, 3.441 85726, 85755, 85741, 0.048, 3.177 85756, 85785, 85771, 0.048, 2.914 85787, 85816, 85802, 0.033, 2.764 85817, 85846, 85832, 0.033, 3.195 85846, 85875, 85861, 0.033, 3.314 85877, 85906, 85892, 0.019, 3.433 85907, 85936, 85922, 0.042, 3.453 85937, 85966, 85952, 0.042, 4.137 85967, 85996, 85982, 0.023, 3.613 85997, 86026, 86012, 0.023, 3.091 86027, 86056, 86042, 0.023, 2.010 86057, 86086, 86072, 0.001, 1.975 86087, 86116, 86102, 0.001, 1.903 86117, 86146, 86132, 0.029, 1.830 86147, 86176, 86162, 0.048, 2.576 86177, 86206, 86192, 0.048, 2.220 86207, 86236, 86222, 0.045, 2.713 86238, 86267, 86253, 0.045, 3.206 86268, 86297, 86283, 0.045, 4.306 86298, 86327, 86313, -0.005, 3.485 86328, 86357, 86343, -0.005, 3.016 86358, 86387, 86373, -0.022, 2.548 86388, 86417, 86403, 0.020, 2.674 86418, 86447, 86433, 0.020, 2.118 86448, 86477, 86463, 0.047, 2.061 86478, 86507, 86493, 0.047, 2.003 86508, 86537, 86523, 0.047, 1.428 86538, 86567, 86553, -0.008, 2.343 86568, 86597, 86583, 0.016, 1.873 86598, 86627, 86613, 0.016, 1.405 86628, 86657, 86643, 0.016, 1.601 86659, 86688, 86674, -0.001, 2.317 86689, 86718, 86704, -0.001, 2.289 86719, 86748, 86734, 0.020, 2.262 86749, 86778, 86764, 0.020, 1.760 86779, 86808, 86794, 0.011, 1.516 86809, 86838, 86824, -9999.000, -9999.000 86839, 86868, 86854, -9999.000, -9999.000 86869, 86898, 86884, -9999.000, -9999.000 86899, 86928, 86914, -9999.000, 3.533 86929, 86958, 86944, -9999.000, 2.920 86959, 86988, 86974, 0.048, 2.301 86989, 87018, 87004, 0.028, 2.244 87019, 87048, 87034, 0.028, 2.351 87049, 87078, 87064, 0.050, 2.228 87079, 87108, 87094, 0.050, 2.107 87109, 87138, 87124, 0.050, 3.124 87140, 87169, 87155, 0.050, 4.414 87170, 87199, 87185, 0.050, 4.653 87200, 87229, 87215, 0.059, 4.895 87230, 87259, 87245, 0.038, 3.925 87260, 87289, 87275, 0.038, 3.888 87290, 87319, 87305, 0.031, 3.693 87320, 87349, 87335, 0.031, 3.498 87350, 87379, 87365, 0.012, 2.944 87380, 87409, 87395, 0.012, 2.649 87410, 87439, 87425, 0.012, 2.681 87441, 87470, 87456, 0.023, 2.712 87471, 87500, 87486, 0.023, 3.706 87501, 87530, 87516, 0.030, 3.759 87531, 87560, 87546, 0.005, 3.635 87561, 87590, 87576, 0.005, 3.513 87591, 87620, 87606, 0.020, 3.454 87621, 87650, 87636, 0.020, 3.511 87651, 87680, 87666, 0.020, 3.397 87681, 87710, 87696, 0.027, 3.283 87711, 87740, 87726, 0.019, 3.908 87741, 87770, 87756, 0.019, 3.313 87771, 87800, 87786, 0.030, 3.370 87801, 87830, 87816, 0.030, 3.427 87831, 87860, 87846, 0.030, 3.725 87862, 87891, 87877, 0.043, 3.701 87892, 87921, 87907, 0.043, 3.704 87922, 87951, 87937, 0.056, 3.706 87952, 87981, 87967, 0.067, 3.882 87982, 88011, 87997, 0.067, 3.024 88012, 88041, 88027, 0.049, 3.238 88042, 88071, 88057, 0.049, 3.452 88072, 88101, 88087, 0.049, 3.561 88102, 88131, 88117, 0.039, 3.143 88132, 88161, 88147, 0.039, 3.217 88162, 88191, 88177, 0.030, 3.291 88192, 88221, 88207, 0.043, 3.742 88222, 88251, 88237, 0.043, 3.666 88252, 88281, 88267, 0.061, 3.440 88283, 88312, 88298, 0.061, 3.214 88313, 88342, 88328, 0.061, 3.132 88343, 88372, 88358, 0.055, 4.272 88373, 88402, 88388, 0.025, 3.889 88403, 88432, 88418, 0.025, 3.508 88433, 88462, 88448, 0.029, 3.160 88463, 88492, 88478, 0.029, 3.943 88493, 88522, 88508, 0.029, 3.661 88523, 88552, 88538, 0.046, 3.379 88553, 88582, 88568, 0.046, 3.238 88583, 88612, 88598, 0.043, 3.440 88613, 88642, 88628, 0.041, 3.471 88643, 88672, 88658, 0.041, 3.502 88673, 88702, 88688, 0.041, 3.488 88704, 88733, 88719, 0.037, 3.882 88734, 88763, 88749, 0.037, 3.649 88764, 88793, 88779, 0.056, 3.415 88794, 88823, 88809, 0.056, 4.109 88824, 88853, 88839, 0.039, 3.405 88854, 88883, 88869, 0.039, 3.099 88884, 88913, 88899, 0.039, 2.794 88914, 88943, 88929, 0.051, 3.225 88944, 88973, 88959, 0.051, 3.248 88974, 89003, 88989, 0.051, 3.096 89004, 89033, 89019, 0.036, 2.942 89034, 89063, 89049, 0.036, 3.555 89064, 89093, 89079, 0.037, 3.114 89095, 89124, 89110, 0.075, 2.891 89125, 89154, 89140, 0.075, 2.669 89155, 89184, 89170, 0.055, 3.115 89185, 89214, 89200, 0.055, 3.334 89215, 89244, 89230, 0.055, 3.085 89245, 89274, 89260, 0.065, 2.836 89275, 89304, 89290, 0.065, 2.941 89305, 89334, 89320, 0.063, 3.109 89335, 89364, 89350, 0.063, 2.778 89365, 89394, 89380, 0.036, 2.446 89395, 89424, 89410, 0.046, 2.462 89425, 89454, 89440, 0.046, 2.452 89455, 89484, 89470, 0.046, 2.392 89486, 89515, 89501, 0.056, 2.331 89516, 89545, 89531, 0.056, 3.104 89546, 89575, 89561, 0.052, 2.498 89576, 89605, 89591, 0.028, 2.286 89606, 89635, 89621, 0.028, 2.075 89636, 89665, 89651, 0.028, 2.525 89666, 89695, 89681, 0.014, 3.018 89696, 89725, 89711, 0.014, 2.518 89726, 89755, 89741, 0.016, 2.015 89756, 89785, 89771, 0.016, 2.700 89786, 89815, 89801, 0.026, 2.263 89816, 89845, 89831, 0.026, 2.084 89846, 89875, 89861, 0.026, 1.905 89876, 89905, 89891, 0.019, 1.891 89907, 89936, 89922, 0.019, 2.186 89937, 89966, 89952, 0.019, 2.002 89967, 89996, 89982, 0.006, 1.817 89997, 90026, 90012, 0.020, 1.692 90027, 90056, 90042, 0.020, 2.283 90057, 90086, 90072, 0.022, 2.036 90087, 90116, 90102, 0.022, 1.790 90117, 90146, 90132, 0.022, 2.096 90147, 90176, 90162, -0.005, 1.858 90177, 90206, 90192, -0.005, 1.653 90207, 90236, 90222, 0.014, 1.447 90237, 90266, 90252, 0.014, 1.979 90267, 90296, 90282, 0.021, 1.252 90298, 90327, 90313, -0.018, 1.167 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