41, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2016, 08, 12, 2017, 06, 06 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 22 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #6 -- CHC - PUQ ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R1 R1: Final Data Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 80144, 80173, 80158, -9999.000, -9999.000, 1.146 80174, 80203, 80188, -9999.000, -9999.000, 0.979 80204, 80233, 80218, -9999.000, -9999.000, 3.130 80235, 80264, 80249, -9999.000, -9999.000, 1.800 80265, 80294, 80279, -9999.000, -9999.000, 3.001 80295, 80324, 80309, -9999.000, -9999.000, 2.844 80325, 80354, 80339, -9999.000, -9999.000, 4.335 80355, 80384, 80369, -9999.000, -9999.000, 2.008 80385, 80414, 80399, -9999.000, -9999.000, 1.831 80415, 80444, 80429, -9999.000, -9999.000, 1.689 80445, 80474, 80459, -9999.000, -9999.000, 2.032 80475, 80504, 80489, -9999.000, -9999.000, 0.756 80505, 80534, 80519, -9999.000, -9999.000, 0.147 80535, 80564, 80549, 0.037, 6.180, 2.438 80565, 80594, 80579, 0.037, 4.177, 1.762 80595, 80624, 80609, 0.044, 2.180, 1.132 80625, 80654, 80639, 0.044, 3.625, 0.876 80656, 80685, 80670, 0.055, 3.010, 2.297 80685, 80714, 80699, 0.055, 2.805, 1.013 80715, 80744, 80729, 0.069, 2.601, 1.097 80746, 80775, 80760, 0.069, 2.592, 2.429 80776, 80805, 80790, 0.045, 1.925, 1.986 80806, 80835, 80820, 0.045, 1.782, 1.198 80836, 80865, 80850, 0.021, 1.638, 0.846 80866, 80895, 80880, 0.021, 1.801, 1.385 80896, 80925, 80910, 0.037, 1.364, 0.524 80926, 80955, 80940, 0.037, 1.559, 1.725 80956, 80985, 80970, 0.034, 1.754, 0.857 80986, 81015, 81000, 0.034, 1.463, 1.473 81016, 81045, 81030, 0.054, 2.018, 1.287 81046, 81075, 81060, -9999.000, -9999.000, 1.370 81076, 81105, 81090, 0.033, 1.992, 0.497 81106, 81135, 81120, 0.033, 2.462, 1.101 81136, 81165, 81150, 0.040, 1.736, 1.812 81166, 81195, 81180, 0.040, 1.795, 0.973 81196, 81225, 81210, 0.033, 1.853, 0.751 81227, 81256, 81241, 0.033, 2.476, 0.864 81257, 81286, 81271, -0.033, 2.062, 0.913 81287, 81316, 81301, -9999.000, -9999.000, 1.921 81317, 81346, 81331, -9999.000, -9999.000, 2.070 81347, 81376, 81361, -9999.000, -9999.000, 0.268 81377, 81406, 81391, 0.034, 2.446, 1.387 81407, 81436, 81421, 0.034, 2.616, 0.895 81437, 81466, 81451, 0.039, 2.783, 2.035 81467, 81496, 81481, 0.039, 2.646, 1.275 81497, 81526, 81511, 0.067, 2.922, 0.721 81527, 81556, 81541, 0.067, 2.766, 1.148 81558, 81587, 81572, 0.065, 2.609, 0.611 81588, 81617, 81602, 0.065, 2.509, 1.058 81618, 81647, 81632, 0.065, 2.655, 0.787 81648, 81677, 81662, 0.065, 2.597, 0.833 81678, 81707, 81692, 0.061, 2.539, 1.487 81708, 81737, 81722, 0.061, 2.713, 1.016 81738, 81767, 81752, 0.078, 1.956, 0.119 81768, 81797, 81782, 0.078, 1.817, 1.271 81798, 81827, 81812, 0.068, 1.676, 0.600 81828, 81857, 81842, 0.068, 2.500, 1.484 81858, 81887, 81872, 0.059, 2.625, 1.059 81888, 81917, 81902, 0.059, 2.304, 0.761 81919, 81948, 81933, 0.057, 1.983, 0.975 81949, 81978, 81963, 0.057, 2.539, 1.015 81979, 82008, 81993, 0.084, 2.266, -0.142 82009, 82038, 82023, 0.084, 2.264, 0.112 82039, 82068, 82053, 0.065, 2.261, 0.912 82069, 82098, 82083, 0.065, 1.982, 0.731 82099, 82128, 82113, 0.079, 2.083, 1.061 82129, 82158, 82143, 0.079, 2.196, 1.526 82159, 82188, 82173, 0.070, 2.310, -9999.000 82189, 82218, 82203, 0.070, 2.517, 1.301 82219, 82248, 82233, 0.060, 2.483, 1.358 82249, 82278, 82263, 0.060, 2.670, 0.577 82279, 82308, 82293, 0.074, 2.857, 0.178 82309, 82338, 82323, 0.074, 2.272, 0.336 82339, 82368, 82353, 0.024, 2.642, -9999.000 82370, 82399, 82384, 0.024, 2.438, 1.310 82400, 82429, 82414, 0.042, 2.235, 0.444 82430, 82459, 82444, 0.042, 2.564, 0.467 82460, 82489, 82474, 0.025, 2.347, 0.879 82490, 82519, 82504, 0.025, 2.092, 0.902 82520, 82549, 82534, 0.023, 1.836, -0.453 82550, 82579, 82564, 0.023, 2.128, -0.324 82580, 82609, 82594, 0.033, 2.301, 1.036 82610, 82639, 82624, 0.033, 2.512, -0.151 82640, 82669, 82654, 0.030, 2.721, 0.771 82670, 82699, 82684, 0.030, 2.824, 0.328 82700, 82729, 82714, 0.018, 3.172, 0.753 82730, 82759, 82744, 0.018, 2.626, -0.356 82761, 82790, 82775, 0.036, 2.074, 0.780 82790, 82819, 82804, 0.036, 3.213, 0.340 82820, 82849, 82834, 0.040, 2.822, 1.157 82851, 82880, 82865, 0.040, 3.092, 0.737 82881, 82910, 82895, 0.023, 3.361, 0.454 82911, 82940, 82925, 0.023, 5.562, 0.877 82941, 82970, 82955, 0.038, 5.092, 0.848 82971, 83000, 82985, 0.038, 6.005, 1.500 83001, 83030, 83015, 0.042, 6.921, 1.491 83031, 83060, 83045, 0.042, 6.953, 3.798 83061, 83090, 83075, 0.051, 9.225, 0.466 83091, 83120, 83105, 0.051, 10.799, 0.584 83121, 83150, 83135, 0.059, 12.362, 2.290 83151, 83180, 83165, 0.059, 13.999, 1.416 83182, 83211, 83196, 0.054, 12.218, 1.691 83212, 83241, 83226, 0.054, 11.264, 3.731 83242, 83271, 83256, 0.024, 10.311, 3.405 83272, 83301, 83286, 0.024, 10.453, 2.518 83302, 83331, 83316, 0.061, 12.745, 2.838 83332, 83361, 83346, 0.061, 10.368, 2.211 83362, 83391, 83376, 0.061, 7.990, 1.191 83502, 83531, 83516, 0.019, 11.731, -9999.000 83532, 83561, 83546, 0.019, 10.663, 1.985 83562, 83591, 83576, 0.019, 10.704, 2.365 83592, 83621, 83606, 0.038, 10.745, 0.983 83622, 83651, 83636, 0.038, 11.675, 2.641 83652, 83681, 83666, -9999.000, -9999.000, 2.509 83682, 83711, 83696, -9999.000, -9999.000, 2.266 83712, 83741, 83726, -9999.000, -9999.000, 0.099 83742, 83771, 83756, -9999.000, -9999.000, 2.390 83773, 83802, 83787, -9999.000, -9999.000, 1.540 83803, 83832, 83817, -9999.000, -9999.000, 0.875 83833, 83862, 83847, -9999.000, -9999.000, 0.767 83863, 83892, 83877, -9999.000, -9999.000, 2.884 83893, 83922, 83907, -9999.000, -9999.000, 1.702 83923, 83952, 83937, -9999.000, -9999.000, 2.139 83953, 83982, 83967, -9999.000, -9999.000, 0.991 83983, 84012, 83997, -9999.000, -9999.000, 0.961 84013, 84042, 84027, -9999.000, -9999.000, 1.258 84043, 84072, 84057, -9999.000, -9999.000, 0.523 84073, 84102, 84087, -9999.000, -9999.000, 1.127 84103, 84132, 84117, -9999.000, -9999.000, 0.232 84133, 84162, 84147, -9999.000, -9999.000, 0.384 84164, 84193, 84178, -9999.000, -9999.000, 0.731 84194, 84223, 84208, -9999.000, -9999.000, 1.097 84224, 84253, 84238, -9999.000, -9999.000, 0.422 84254, 84283, 84268, -9999.000, -9999.000, 0.956 84284, 84313, 84298, -9999.000, -9999.000, 1.690 84314, 84343, 84328, -9999.000, -9999.000, 0.800 84344, 84373, 84358, -9999.000, -9999.000, 0.283 84374, 84403, 84388, -9999.000, -9999.000, -0.043 84404, 84433, 84418, -9999.000, -9999.000, -0.179 84434, 84463, 84448, -9999.000, -9999.000, 1.514 84464, 84493, 84478, -9999.000, -9999.000, 1.291 84494, 84523, 84508, -9999.000, -9999.000, 0.647 84524, 84553, 84538, -9999.000, -9999.000, 1.744 84554, 84583, 84568, -9999.000, -9999.000, 1.433 84584, 84613, 84598, -9999.000, -9999.000, 0.322 84614, 84643, 84628, -9999.000, -9999.000, 1.124 84645, 84674, 84659, -9999.000, -9999.000, 0.819 84675, 84704, 84689, -9999.000, -9999.000, 0.480 84705, 84734, 84719, -9999.000, -9999.000, 0.489 84735, 84764, 84749, -9999.000, -9999.000, 0.910 84765, 84794, 84779, -9999.000, -9999.000, 0.479 84795, 84824, 84809, -9999.000, -9999.000, 0.784 84825, 84854, 84839, -9999.000, -9999.000, 0.023 84855, 84884, 84869, -9999.000, -9999.000, 0.152 84885, 84914, 84899, -9999.000, -9999.000, 1.315 84915, 84944, 84929, -9999.000, -9999.000, 0.920 84945, 84974, 84959, -9999.000, -9999.000, 0.067 84975, 85004, 84989, -9999.000, -9999.000, 0.343 85005, 85034, 85019, -9999.000, -9999.000, 1.503 85035, 85064, 85049, 0.035, -9999.000, 0.541 85066, 85095, 85080, 0.035, 4.424, 0.738 85096, 85125, 85110, 0.029, 3.833, 0.350 85126, 85155, 85140, 0.029, 3.592, 1.073 85156, 85185, 85170, 0.057, 3.349, 0.419 85186, 85215, 85200, 0.057, 3.541, 0.593 85216, 85245, 85230, 0.032, 3.626, 0.919 85246, 85275, 85260, 0.032, 3.409, 0.780 85276, 85305, 85290, 0.051, 3.193, -0.328 85306, 85335, 85320, 0.051, 3.825, 0.865 85336, 85365, 85350, 0.049, 3.818, 0.596 85366, 85395, 85380, 0.049, 3.875, 0.413 85396, 85425, 85410, 0.032, 3.933, 1.445 85426, 85455, 85440, 0.032, 4.424, 0.570 85457, 85486, 85471, 0.050, 4.050, 0.318 85487, 85516, 85501, 0.050, 3.948, 0.354 85517, 85546, 85531, 0.033, 3.847, 0.866 85547, 85576, 85561, 0.033, 3.543, 0.799 85577, 85606, 85591, 0.050, 3.135, 0.439 85607, 85636, 85621, 0.050, 3.137, 0.561 85637, 85666, 85651, 0.047, 3.140, 0.547 85667, 85696, 85681, 0.047, 3.081, 0.323 85697, 85726, 85711, 0.029, 3.115, 0.247 85727, 85756, 85741, 0.029, 2.853, 0.238 85757, 85786, 85771, 0.034, 2.592, 0.244 85788, 85817, 85802, 0.034, 2.393, 0.950 85818, 85847, 85832, 0.014, 2.774, 0.721 85847, 85876, 85861, 0.014, 2.843, 0.503 85878, 85907, 85892, 0.045, 2.913, 0.482 85908, 85937, 85922, 0.045, 2.897, 0.949 85938, 85967, 85952, 0.040, 3.409, 0.514 85968, 85997, 85982, 0.040, 3.066, 0.368 85998, 86027, 86012, 0.029, 2.725, -0.125 86028, 86057, 86042, 0.029, 1.865, 0.849 86058, 86087, 86072, -0.006, 1.947, 0.048 86088, 86117, 86102, -0.006, 1.968, -0.055 86118, 86147, 86132, 0.027, 1.990, 0.667 86148, 86177, 86162, 0.027, 2.965, 0.090 86178, 86207, 86192, 0.032, 2.727, 1.241 86208, 86237, 86222, 0.032, 3.521, 1.759 86239, 86268, 86253, 0.040, 4.314, 3.061 86269, 86298, 86283, 0.040, 6.875, 0.042 86299, 86328, 86313, -0.001, 8.297, -0.116 86329, 86358, 86343, -0.001, 7.477, -0.542 86359, 86388, 86373, 0.000, 6.657, 1.545 86389, 86418, 86403, 0.000, 7.990, 1.945 86419, 86448, 86433, 0.041, 6.853, 0.945 86449, 86478, 86463, 0.041, 6.717, 1.583 86479, 86508, 86493, 0.036, 6.581, 1.427 86509, 86538, 86523, 0.036, 4.885, 0.307 86539, 86568, 86553, 0.021, 7.766, 0.726 86569, 86598, 86583, 0.021, 6.130, 2.227 86599, 86628, 86613, 0.021, 4.499, 1.413 86629, 86658, 86643, 0.021, 5.269, 0.795 86660, 86689, 86674, 0.014, 6.850, 0.741 86690, 86719, 86704, 0.014, 6.422, 0.751 86720, 86749, 86734, 0.020, 5.991, 1.514 86750, 86779, 86764, 0.020, 4.675, 2.595 86780, 86809, 86794, -0.058, -9999.000, 0.618 86810, 86839, 86824, -9999.000, -9999.000, 1.533 86840, 86869, 86854, -9999.000, -9999.000, 1.393 86870, 86899, 86884, -9999.000, -9999.000, 1.767 86900, 86929, 86914, 0.034, 5.338, 2.989 86930, 86959, 86944, 0.034, 4.223, 2.076 86960, 86989, 86974, 0.040, 3.096, 1.351 86990, 87019, 87004, 0.040, 2.692, 1.328 87020, 87049, 87034, 0.022, 2.738, 0.747 87050, 87079, 87064, 0.022, 2.496, 1.858 87080, 87109, 87094, 0.030, 2.256, 1.068 87110, 87139, 87124, 0.030, 3.081, 0.160 87141, 87170, 87155, 0.057, 4.067, 1.504 87171, 87200, 87185, 0.057, 4.238, 0.288 87201, 87230, 87215, 0.056, 4.411, -9999.000 87231, 87260, 87245, 0.056, 3.576, 0.803 87261, 87290, 87275, 0.048, 3.540, -0.012 87291, 87320, 87305, 0.048, 3.372, 0.028 87321, 87350, 87335, 0.015, 3.204, 0.400 87351, 87380, 87365, 0.015, 2.724, -0.490 87381, 87410, 87395, 0.024, 2.422, 1.706 87411, 87440, 87425, 0.024, 2.492, 0.976 87442, 87471, 87456, 0.035, 2.562, 0.018 87472, 87501, 87486, 0.035, 3.441, 0.942 87502, 87531, 87516, 0.034, 3.496, -0.060 87532, 87561, 87546, 0.034, 3.360, 0.811 87562, 87591, 87576, 0.021, 3.226, 0.773 87592, 87621, 87606, 0.021, 3.168, 0.583 87622, 87651, 87636, 0.036, 3.193, -0.201 87652, 87681, 87666, 0.036, 3.081, 0.902 87682, 87711, 87696, 0.027, 2.969, 0.805 87712, 87741, 87726, 0.027, 3.524, 0.482 87742, 87771, 87756, 0.047, 2.999, 0.051 87772, 87801, 87786, 0.047, 3.071, 0.604 87802, 87831, 87816, 0.038, 3.142, 0.516 87832, 87861, 87846, 0.038, 3.475, 0.273 87863, 87892, 87877, 0.049, 3.496, 0.587 87893, 87922, 87907, 0.049, 3.527, 0.314 87923, 87952, 87937, 0.069, 3.558, 0.963 87953, 87982, 87967, 0.069, 3.808, 1.019 87983, 88012, 87997, 0.061, 3.113, 0.875 88013, 88042, 88027, 0.061, 3.391, 0.383 88043, 88072, 88057, 0.041, 3.668, 0.568 88073, 88102, 88087, 0.041, 3.799, -9999.000 88103, 88132, 88117, 0.042, 3.471, 0.682 88133, 88162, 88147, 0.042, 3.514, 0.751 88163, 88192, 88177, 0.048, 3.556, 0.126 88193, 88222, 88207, 0.048, 3.987, 0.487 88223, 88252, 88237, 0.047, 3.848, 0.111 88253, 88282, 88267, 0.047, 3.653, -0.036 88284, 88313, 88298, 0.054, 3.459, 0.268 88314, 88343, 88328, 0.054, 3.378, 0.398 88344, 88373, 88358, 0.065, 4.600, -0.111 88374, 88403, 88388, 0.065, 4.212, 1.852 88404, 88433, 88418, 0.032, 3.826, 0.564 88434, 88463, 88448, 0.032, 3.424, 0.214 88464, 88493, 88478, 0.029, 4.200, 0.099 88494, 88523, 88508, 0.029, 3.895, 1.052 88524, 88553, 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