41, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2016, 08, 01, 2017, 06, 06 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 22 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #2 -- PMD - ANC ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R1 R1: Final Data Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 57617, 57646, 57631, -9999.000, -9999.000, 0.070 57647, 57676, 57661, 0.266, 6.758, 0.870 57677, 57706, 57691, 0.266, 5.822, 0.320 57707, 57736, 57721, 0.263, 5.795, -0.013 57737, 57766, 57751, 0.263, 7.079, 1.288 57767, 57796, 57781, 0.225, 8.364, 0.530 57797, 57826, 57811, 0.225, 7.923, 0.395 57828, 57857, 57842, 0.345, 6.723, 0.442 57858, 57887, 57872, 0.345, 7.275, 0.650 57888, 57917, 57902, 0.240, 7.826, 0.677 57918, 57947, 57932, 0.240, 8.794, -0.061 57948, 57977, 57962, 0.277, 8.033, 0.546 57978, 58007, 57992, 0.277, 8.318, -0.290 58008, 58037, 58022, 0.265, 8.602, 0.178 58038, 58067, 58052, 0.265, 9.354, 0.925 58068, 58097, 58082, 0.215, 10.209, 0.598 58098, 58127, 58112, 0.215, 9.038, 0.652 58128, 58157, 58142, 0.259, 7.871, 0.082 58159, 58188, 58173, 0.259, 8.682, 0.831 58189, 58218, 58203, 0.307, 8.886, -0.040 58219, 58248, 58233, 0.307, 7.854, 0.238 58249, 58278, 58263, 0.349, 6.823, 0.316 58279, 58308, 58293, 0.349, 6.293, 0.310 58309, 58338, 58323, 0.339, 6.290, 0.405 58339, 58368, 58353, 0.339, 5.813, 0.680 58369, 58398, 58383, 0.365, 5.339, 0.352 58399, 58428, 58413, 0.365, 5.390, 0.238 58429, 58458, 58443, 0.352, 6.167, 0.603 58459, 58488, 58473, 0.352, 6.739, 0.522 58489, 58518, 58503, 0.353, 7.311, 0.337 58519, 58548, 58533, 0.353, 10.058, 0.320 58549, 58578, 58563, 0.222, 11.483, 0.559 58580, 58609, 58594, 0.222, 10.534, 0.783 58610, 58639, 58624, 0.260, 9.592, -0.041 58640, 58669, 58654, 0.260, 12.160, -0.117 58670, 58699, 58684, 0.212, 11.613, 0.625 58700, 58729, 58714, 0.212, 10.790, 0.085 58730, 58759, 58744, 0.286, 9.965, 0.521 58760, 58789, 58774, 0.286, 11.516, -9999.000 58790, 58819, 58804, 0.275, 11.150, 0.158 58820, 58849, 58834, 0.275, 10.430, 0.424 58850, 58879, 58864, 0.323, 9.716, 0.764 58880, 58909, 58894, 0.323, 10.847, 0.364 58910, 58939, 58924, 0.206, 10.411, 0.016 58940, 58969, 58954, 0.206, 10.933, 0.483 58970, 58999, 58984, 0.184, 11.456, 0.333 59001, 59030, 59015, 0.184, 10.975, -0.238 59031, 59060, 59045, 0.330, 11.590, 0.632 59061, 59090, 59075, 0.330, 10.659, -0.216 59091, 59120, 59105, 0.327, 9.728, 0.436 59121, 59150, 59135, 0.327, 10.420, 0.245 59151, 59180, 59165, 0.333, 11.661, 0.097 59181, 59210, 59195, 0.333, 11.481, 0.795 59211, 59240, 59225, 0.241, 11.301, -0.531 59241, 59270, 59255, 0.241, 11.238, 0.271 59271, 59300, 59285, 0.265, 11.328, 0.144 59301, 59330, 59315, 0.265, 11.071, 0.546 59331, 59360, 59345, 0.314, 10.809, 0.391 59361, 59390, 59375, 0.314, 11.968, 0.377 59391, 59420, 59405, 0.243, 12.745, 0.341 59422, 59451, 59436, 0.243, 11.827, 0.262 59451, 59480, 59465, 0.231, 10.911, 1.049 59482, 59511, 59496, 0.231, 10.637, -0.000 59512, 59541, 59526, 0.296, 10.578, -9999.000 59542, 59571, 59556, 0.296, 10.191, 0.372 59572, 59601, 59586, 0.269, 9.801, 0.395 59602, 59631, 59616, 0.269, 10.100, 0.287 59632, 59661, 59646, 0.217, 9.178, 0.121 59662, 59691, 59676, 0.217, 10.104, 0.869 59692, 59721, 59706, 0.136, 11.027, 0.583 59722, 59751, 59736, 0.136, 11.929, 0.465 59752, 59781, 59766, 0.258, 12.338, 0.178 59782, 59811, 59796, 0.258, 12.161, 0.851 59812, 59841, 59826, 0.172, 11.985, -0.031 59842, 59871, 59856, 0.172, 12.771, 0.284 59873, 59902, 59887, 0.213, 12.185, -0.106 59903, 59932, 59917, 0.213, 10.633, 0.096 59933, 59962, 59947, 0.210, 9.087, 0.597 59963, 59992, 59977, 0.210, 8.749, 0.443 59993, 60022, 60007, 0.260, 8.729, 0.220 60023, 60052, 60037, 0.260, 8.086, -0.007 60053, 60082, 60067, 0.296, 7.441, 0.425 60083, 60112, 60097, 0.296, 10.003, -0.088 60113, 60142, 60127, 0.213, 8.313, -0.184 60143, 60172, 60157, 0.213, 9.226, -0.131 60173, 60202, 60187, 0.156, 10.133, -0.166 60203, 60232, 60217, 0.156, 7.680, 0.549 60233, 60262, 60247, 0.179, 10.705, 0.243 60263, 60292, 60277, 0.179, 10.262, -9999.000 60293, 60322, 60307, 0.189, 9.819, 0.606 60324, 60353, 60338, 0.189, 10.571, -0.405 60354, 60383, 60368, 0.243, 11.265, 0.787 60384, 60413, 60398, 0.243, 10.891, 0.135 60414, 60443, 60428, 0.212, 10.517, 0.162 60444, 60473, 60458, 0.212, 7.979, 0.034 60474, 60503, 60488, 0.297, 6.264, 0.495 60504, 60533, 60518, 0.297, 6.541, 0.346 60534, 60563, 60548, 0.330, 6.818, 0.309 60564, 60593, 60578, 0.330, 5.524, 0.152 60594, 60623, 60608, 0.230, 4.998, 0.441 60624, 60653, 60638, 0.230, 4.798, 0.246 60654, 60683, 60668, 0.250, 4.598, 0.118 60684, 60713, 60698, 0.250, 5.335, -0.219 60714, 60743, 60728, 0.301, 6.054, 0.634 60744, 60773, 60758, 0.301, 6.635, -0.035 60774, 60803, 60788, 0.247, 7.215, 0.168 60805, 60834, 60819, 0.247, 12.025, 0.390 60835, 60864, 60849, 0.175, 13.486, 0.206 60865, 60894, 60879, 0.175, 11.672, 0.762 60895, 60924, 60909, 0.200, 9.846, -0.357 60925, 60954, 60939, 0.200, 11.880, 0.138 60955, 60984, 60969, 0.188, 11.374, 0.496 60985, 61014, 60999, 0.188, 9.600, -9999.000 61015, 61044, 61029, 0.256, 7.826, 0.703 61045, 61074, 61059, 0.256, 7.309, 0.329 61075, 61104, 61089, 0.233, 7.530, 0.093 61105, 61134, 61119, 0.233, 7.641, 0.048 61136, 61165, 61150, 0.240, 7.752, 0.538 61166, 61195, 61180, 0.240, 7.146, 0.044 61196, 61225, 61210, 0.266, 8.478, -0.533 61226, 61255, 61240, 0.266, 7.267, 0.899 61256, 61285, 61270, 0.242, 6.059, -0.085 61286, 61315, 61300, 0.242, 8.897, 0.552 61316, 61345, 61330, 0.256, 8.684, 0.114 61346, 61375, 61360, 0.256, 9.055, 0.071 61376, 61405, 61390, 0.177, 9.429, 0.224 61406, 61435, 61420, 0.177, 10.344, 0.568 61436, 61465, 61450, 0.186, 10.179, -0.164 61466, 61495, 61480, 0.186, 10.023, 0.601 61496, 61525, 61510, 0.145, 9.867, 0.436 61526, 61555, 61540, 0.145, 10.169, -0.447 61557, 61586, 61571, 0.111, 10.309, 0.027 61587, 61616, 61601, 0.111, 10.260, 0.079 61617, 61646, 61631, 0.313, 10.210, 0.096 61647, 61676, 61661, 0.313, 10.915, -0.312 61677, 61706, 61691, 0.119, 10.878, -0.056 61707, 61736, 61721, 0.119, 10.479, 0.598 61737, 61766, 61751, 0.152, 10.078, -0.320 61767, 61796, 61781, 0.152, 11.706, -0.106 61797, 61826, 61811, 0.111, 12.035, -0.025 61827, 61856, 61841, 0.111, 11.202, 0.562 61857, 61886, 61871, 0.167, 10.372, -0.060 61887, 61916, 61901, 0.167, 10.644, -9999.000 61917, 61946, 61931, 0.148, 11.788, -0.316 61947, 61976, 61961, 0.148, 10.692, 0.664 61978, 62007, 61992, 0.146, 9.590, 0.413 62008, 62037, 62022, 0.146, 11.313, -0.487 62038, 62067, 62052, 0.151, 9.751, 0.703 62068, 62097, 62082, 0.151, 9.425, -0.294 62098, 62127, 62112, 0.178, 9.102, -0.330 62128, 62157, 62142, 0.178, 11.163, 0.494 62158, 62187, 62172, 0.140, 11.114, 0.482 62188, 62217, 62202, 0.140, 9.865, 0.712 62218, 62247, 62232, 0.209, 8.611, 0.664 62248, 62277, 62262, 0.209, 8.676, 0.290 62278, 62307, 62292, 0.229, 9.749, -9999.000 62308, 62337, 62322, 0.229, 8.725, 0.336 62338, 62367, 62352, 0.251, 7.702, -9999.000 62368, 62397, 62382, 0.251, 8.868, -9999.000 62399, 62428, 62413, 0.207, 7.783, -0.065 62429, 62458, 62443, 0.207, 8.235, -9999.000 62459, 62488, 62473, 0.159, 8.687, -9999.000 62489, 62518, 62503, 0.159, 8.975, -9999.000 62519, 62548, 62533, 0.087, 9.669, -9999.000 62549, 62578, 62563, 0.087, 9.053, 0.650 62579, 62608, 62593, 0.110, 8.436, -9999.000 62609, 62638, 62623, 0.110, 9.002, 0.466 62639, 62668, 62653, 0.140, 8.238, -9999.000 62669, 62698, 62683, 0.140, 7.907, 0.388 62699, 62728, 62713, 0.130, 7.576, -9999.000 62729, 62758, 62743, 0.130, 8.163, 0.671 62759, 62788, 62773, 0.141, 9.111, -9999.000 62789, 62818, 62803, 0.141, 8.184, -9999.000 62820, 62849, 62834, 0.099, 7.250, -9999.000 62850, 62879, 62864, 0.099, 7.433, -9999.000 62880, 62909, 62894, 0.119, 8.283, -9999.000 62910, 62939, 62924, 0.119, 7.268, -9999.000 62940, 62969, 62954, 0.118, 6.257, -9999.000 62970, 62999, 62984, 0.118, 8.211, -9999.000 63000, 63029, 63014, 0.086, 9.030, 0.170 63030, 63059, 63044, 0.086, 8.408, -9999.000 63060, 63089, 63074, 0.137, 7.782, -9999.000 63090, 63119, 63104, 0.137, 9.076, -9999.000 63193, 63222, 63207, 0.271, 10.940, -9999.000 63223, 63252, 63237, 0.271, 10.741, -9999.000 63253, 63282, 63267, 0.228, 10.544, -9999.000 63283, 63312, 63297, 0.228, 12.162, -0.267 63314, 63343, 63328, 0.156, 11.588, -9999.000 63344, 63373, 63358, 0.156, 10.672, -0.368 63374, 63403, 63388, 0.228, 9.753, -9999.000 63404, 63433, 63418, 0.228, 10.971, -9999.000 63434, 63463, 63448, 0.178, 11.230, -0.185 63464, 63493, 63478, 0.178, 10.496, -9999.000 63494, 63523, 63508, 0.309, 9.766, -9999.000 63524, 63553, 63538, 0.309, 10.824, -9999.000 63554, 63583, 63568, 0.267, 11.320, -0.177 63584, 63613, 63598, 0.267, 10.738, -9999.000 63614, 63643, 63628, 0.255, 10.154, -9999.000 63644, 63673, 63658, 0.255, 10.554, -0.204 63674, 63703, 63688, 0.294, 11.103, -9999.000 63705, 63734, 63719, 0.294, 10.519, -0.297 63734, 63763, 63748, 0.267, 9.942, -9999.000 63765, 63794, 63779, 0.267, 11.637, -9999.000 63795, 63824, 63809, 0.140, 11.795, -9999.000 63825, 63854, 63839, 0.140, 10.170, -9999.000 63855, 63884, 63869, 0.234, 8.539, -9999.000 63885, 63914, 63899, 0.234, 9.065, -9999.000 63915, 63944, 63929, 0.229, 10.478, -9999.000 63945, 63974, 63959, 0.229, 9.768, -9999.000 63975, 64004, 63989, 0.367, 9.063, -9999.000 64005, 64034, 64019, 0.367, 10.657, -9999.000 64035, 64064, 64049, 0.240, 12.862, -9999.000 64065, 64094, 64079, 0.240, 12.271, -9999.000 64095, 64124, 64109, 0.233, 11.678, 0.170 64126, 64155, 64140, 0.233, 13.681, -9999.000 64156, 64185, 64170, 0.268, 12.303, -9999.000 64186, 64215, 64200, 0.268, 11.819, -9999.000 64216, 64245, 64230, 0.218, 11.339, -9999.000 64246, 64275, 64260, 0.218, 12.658, -9999.000 64276, 64305, 64290, 0.432, 10.917, -9999.000 64306, 64335, 64320, 0.432, 10.199, -9999.000 64336, 64365, 64350, 0.427, 9.480, -9999.000 64366, 64395, 64380, 0.427, 8.800, -9999.000 64396, 64425, 64410, 0.441, 8.777, -9999.000 64426, 64455, 64440, 0.441, 7.699, -0.286 64456, 64485, 64470, 0.502, 6.620, -0.225 64486, 64515, 64500, 0.502, 8.810, -0.383 64517, 64546, 64531, 0.560, 11.370, -9999.000 64547, 64576, 64561, 0.560, 11.442, -9999.000 64576, 64605, 64590, 0.556, 11.513, -0.292 64607, 64636, 64621, 0.556, 10.678, -9999.000 64637, 64666, 64651, 0.574, 10.675, -9999.000 64667, 64696, 64681, 0.574, 9.384, -9999.000 64697, 64726, 64711, 0.460, 8.093, -9999.000 64727, 64756, 64741, 0.460, 8.672, -9999.000 64757, 64786, 64771, 0.474, 7.998, -9999.000 64787, 64816, 64801, 0.474, 7.985, -9999.000 64817, 64846, 64831, 0.427, 7.973, -0.244 64847, 64876, 64861, 0.427, 7.390, -0.022 64877, 64906, 64891, 0.443, 7.365, -0.150 64907, 64936, 64921, 0.443, 7.214, -9999.000 64938, 64967, 64952, 0.457, 7.063, -9999.000 64968, 64997, 64982, 0.457, 7.373, -9999.000 64998, 65027, 65012, 0.452, 7.483, -9999.000 65028, 65057, 65042, 0.452, 7.733, -9999.000 65058, 65087, 65072, 0.572, 7.982, -9999.000 65088, 65117, 65102, 0.572, 7.212, -9999.000 65118, 65147, 65132, 0.586, 7.396, -9999.000 65148, 65177, 65162, 0.586, 7.522, -0.029 65178, 65207, 65192, 0.531, 7.650, -9999.000 65208, 65237, 65222, 0.531, 7.475, -9999.000 65238, 65267, 65252, 0.572, 7.122, -9999.000 65268, 65297, 65282, 0.572, 6.529, -9999.000 65298, 65327, 65312, 0.542, 5.938, -9999.000 65328, 65357, 65342, 0.542, 5.809, -9999.000 65359, 65388, 65373, 0.457, 6.615, -9999.000 65389, 65418, 65403, 0.457, 6.514, -0.002 65419, 65448, 65433, 0.604, 6.413, -9999.000 65449, 65478, 65463, 0.604, 5.925, -0.075 65479, 65508, 65493, 0.406, 5.363, -9999.000 65509, 65538, 65523, 0.406, 5.101, -9999.000 65539, 65568, 65553, 0.319, 4.841, -9999.000 65569, 65598, 65583, 0.319, 4.127, -9999.000 65599, 65628, 65613, 0.262, 4.006, -9999.000 65629, 65658, 65643, 0.262, 3.805, -9999.000 65659, 65688, 65673, 0.213, 3.603, -9999.000 65689, 65718, 65703, 0.213, 3.367, -9999.000 65719, 65748, 65733, 0.175, 3.617, -9999.000 65750, 65779, 65764, 0.175, 3.615, -0.206 65780, 65809, 65794, 0.248, 3.613, -9999.000 65810, 65839, 65824, 0.248, 3.784, -0.149 65840, 65869, 65854, 0.246, 3.920, -9999.000 65870, 65899, 65884, 0.246, 3.827, -9999.000 65900, 65929, 65914, 0.301, 3.734, -9999.000 65930, 65959, 65944, 0.301, 3.740, -9999.000 65960, 65989, 65974, 0.278, 4.238, -9999.000 65990, 66019, 66004, 0.278, 4.760, -9999.000 66020, 66049, 66034, 0.372, 5.281, -9999.000 66050, 66079, 66064, 0.372, 4.713, -9999.000 66080, 66109, 66094, 0.352, 4.787, -9999.000 66110, 66139, 66124, 0.352, 5.309, -0.106 66140, 66169, 66154, 0.406, 5.829, -9999.000 66171, 66200, 66185, 0.406, 7.654, -9999.000 66201, 66230, 66215, 0.380, 6.454, -9999.000 66231, 66260, 66245, 0.380, 4.979, -0.114 66261, 66290, 66275, 0.319, 3.504, -9999.000 66291, 66320, 66305, 0.319, 4.106, -9999.000 66321, 66350, 66335, 0.375, 4.445, -9999.000 66351, 66380, 66365, 0.375, 4.643, -9999.000 66381, 66410, 66395, 0.426, 4.841, -9999.000 66411, 66440, 66425, 0.426, 5.487, -0.326 66441, 66470, 66455, 0.391, 5.011, -9999.000 66471, 66500, 66485, 0.391, 4.615, -9999.000 66501, 66530, 66515, 0.330, 4.217, -9999.000 66531, 66560, 66545, 0.330, 4.494, -9999.000 66561, 66590, 66575, 0.342, 4.854, -9999.000 66591, 66620, 66605, 0.342, 5.140, -9999.000 66621, 66650, 66635, 0.390, 5.426, -9999.000 66652, 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